130597-97-6

Basic information

• Product Name: (E)-4-(N,N-dimethylamino)-N-(1-phenylethylidene)aniline
• Synonyms: (E)-4-(N,N-dimethylamino)-N-(1-phenylethylidene)aniline
• CAS NO: 130597-97-6
• Molecular Weight: 238.332
• Mol File: 130597-97-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (E)-4-(N,N-dimethylamino)-N-(1-phenylethylidene)aniline(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-4-(N,N-dimethylamino)-N-(1-phenylethylidene)aniline(130597-97-6)
• EPA Substance Registry System: (E)-4-(N,N-dimethylamino)-N-(1-phenylethylidene)aniline(130597-97-6)

Safety Data

• Hazardous Substances Data: 130597-97-6(Hazardous Substances Data)

Upstream product

• 99-98-9 4-amino-N,N-dimethylaniline 
• 536-74-3 phenylacetylene 
• 1047080-58-9 N,N-Dimethyl-N'-(1-phenyl-ethyl)-benzene-1,4-diamine 
• 98-86-2 acetophenone 
• 4316-37-4 1,1,-diethoxy-1-phenylethane 

Downstream Products

• 91118-63-7 N-<2-(4-(N,N-dimethylamino)phenylimino)-2-phenylethylidene>phenylamine N-oxide 
• 91118-68-2 C₂₂H₂₀ClN₃O 

Relevant articles and documents

Regioselective mercury(I)/palladium(II)-catalyzed single-step approach for the synthesis of imines and 2-substituted indoles

An efficient synthesis of ketimines was achieved through a regioselective Hg(I)-catalyzed hydroamination of terminal acetylenes in the presence of anilines. The Pd(II)-catalyzed cycliza-tion of these imines into the 2-substituted indoles was satisfactorily carried out by a C-H acti-vation. In a single-step approach, a variety of 2-substituted indoles were also generated via a Hg(I)/Pd(II)-catalyzed, one-pot, two-step process, starting from anilines and terminal acetylenes. The arylacetylenes proved to be more effective than the alkyl derivatives.

SYNTHESIS AND 1H NMR SPECTRA OF BENZYLIDENEANILINES WITH STERICALLY INTERACTING SUBSTITUENTS

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