13075-28-0Relevant articles and documents
Malhotra, K. C.,Chaudhry, S. C.
, p. 1547 - 1550 (1981)
Thorium(IV) Fluorosulphate
Paul, R. C.,Singh, Sukhjinder,Verma, R. D.
, p. 24 - 25 (2007/10/02)
Th(SO4F)4, >, has been prepared by the action of H2SO4F on Th(O2CCH3)4,.The i.r. spectrum indicates bidentate nature of SO3F groups.It forms adducts with pyridine (Py), quinoline (Q), dimethylsulphoxide (DMSO), triphenylphosphineoxide (TPPO) and bipyridyl (Bipy) of the compositions, A* 2Py, A* 2Q, A * 2DMSO, A* 2TPPO and A* Bipy respectively.SO2F groups in these complexes are also bidante as shown by their i.r. spectra.Th(SO3F)4 decomposes thermally in a single step with evolution of SO2F2 and formation of Th(SO4)2.