130814-73-2

Basic information

• Product Name: (E)-(1'R)-2-Methyl-3-(1'-phenylethoxy)-propenal
• Synonyms: (E)-(1'R)-2-Methyl-3-(1'-phenylethoxy)-propenal
• CAS NO: 130814-73-2
• Molecular Weight: 190.242
• Mol File: 130814-73-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (E)-(1'R)-2-Methyl-3-(1'-phenylethoxy)-propenal(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-(1'R)-2-Methyl-3-(1'-phenylethoxy)-propenal(130814-73-2)
• EPA Substance Registry System: (E)-(1'R)-2-Methyl-3-(1'-phenylethoxy)-propenal(130814-73-2)

Safety Data

• Hazardous Substances Data: 130814-73-2(Hazardous Substances Data)

Upstream product

• 62055-46-3 3-ethoxy-2-methylacrolein 
• 1517-69-7 (R)-1-phenylethanol 

Downstream Products

• 130814-75-4 (-)-{1-(R)-[(1E)-2-methylbuta-1,3-dienyloxy]ethyl}benzene 
• 149494-77-9 [(S)-1-((E)-2-Methyl-buta-1,3-dienyloxy)-ethyl]-benzene 
• 130814-79-8 (4aR,5S,8aS)-2,3-Dichloro-6-methyl-1,4-dioxo-5-((R)-1-phenyl-ethoxy)-1,4,5,8-tetrahydro-naphthalene-4a,8a-dicarbonitrile 
• 130814-84-5 1,4,4a,9a-Tetrahydro-8-hydroxy-2-methyl-1-(1-phenylethoxy)-9,10-anthraquinone 
• 130814-81-2 (3aS,4R,7aS)-5-Methyl-2-phenyl-4-((R)-1-phenyl-ethoxy)-3a,4,7,7a-tetrahydro-isoindole-1,3-dione 
• 130814-82-3 (1S,4aS,9aS)-2,9a-Dimethyl-1-((R)-1-phenyl-ethoxy)-1,4,4a,9a-tetrahydro-anthraquinone 
• 130814-86-7 (1R,2S,3R)-4-Methyl-3-((R)-1-phenyl-ethoxy)-cyclohex-4-ene-1,2-dicarboxylic acid diethyl ester 
• 130814-83-4 (1R,4aS,9aS)-2-Methyl-1-((R)-1-phenyl-ethoxy)-1,4,4a,9a-tetrahydro-anthraquinone 
• 130814-78-7 (S)-4-Methyl-3-((R)-1-phenyl-ethoxy)-cyclohex-4-ene-1,1,2,2-tetracarbonitrile 
• 130814-80-1 (3aS,4R,7aS)-5-Methyl-4-((R)-1-phenyl-ethoxy)-3a,4,7,7a-tetrahydro-isobenzofuran-1,3-dione 
• 130846-99-0 (1S,2S,6R)-1,6,7,7-Tetrachloro-3-methyl-2-((R)-1-phenyl-ethoxy)-bicyclo[4.1.0]hept-3-ene 
• 130814-85-6 1-[(1S,5R)-4-Methyl-5-((R)-1-phenyl-ethoxy)-cyclohex-3-enyl]-ethanone 

Relevant articles and documents

Asymmetric Diels-Alder Reactions with Chiral 2-Methyl-1-(1-arylethoxy)-1,3-butadienes

Chiral 1-arylethanols 2, prepared by enantioselective reduction of phenones 1 with lithium aluminium hydride and Chirald , are converted to the chiral 2-methyl-1-(1-arylethoxy)-1,3-butadienes 5 by vinylogous transesterification with 2-methyl-1-ethoxyacrolein (3) and subsequent Wittig methylenation of the intermediate chiral 3-(1-arylethoxy)-2-methylacroleins 4.The 1-arylethyl isoprenyl ethers 5 undergo cycloadditions as donor-activated 1,3-dienes with numerous electron-deficient dienophiles in good chemical yields and high diastereomeric excesses (>/= 95percent).The chiral inductor is removed optically pure from the cycloadducts by hydrogen chloride and silica gel in dichloromethane suspension at room temperature.