130894-36-9Relevant articles and documents
A deuterium labelling study into the insertion of diphenylacetylenes into iron-aryl bonds
Butler, Ian R.,Elliot, Joanne L.,Houde, Jean
, p. 1564 - 1573 (2007/10/02)
The mechanism of the reaction of dicarbonyl(η5-cyclopentadienyl)phenyliron, 1, with diphenylacetylene to give 2,3-diphenyl--inden-1-one has been investigated using a partially deuterated 1.The mechanistic pathway of the reaction is discussed in terms of the labelling of the indenones obtained.The reaction of phenylacetylene with 1 gives a mixture of products including 2,4,6-triphenyl-4'-methylbenzophenone and C-4,C-6a-dihydro-4-(4'-methylphenyl)-2-phenylpentalene(1-r-3aH)one.