131011-77-3

Basic information

• Product Name: dicarbonylhydridobis(triethylphosphino)(2,4,6-trimethoxybenzoato)iron
• CAS NO: 131011-77-3
• Molecular Weight: 560.388
• Mol File: 131011-77-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: dicarbonylhydridobis(triethylphosphino)(2,4,6-trimethoxybenzoato)iron(CAS DataBase Reference)
• NIST Chemistry Reference: dicarbonylhydridobis(triethylphosphino)(2,4,6-trimethoxybenzoato)iron(131011-77-3)
• EPA Substance Registry System: dicarbonylhydridobis(triethylphosphino)(2,4,6-trimethoxybenzoato)iron(131011-77-3)

Safety Data

• Hazardous Substances Data: 131011-77-3(Hazardous Substances Data)

Upstream product

• 107654-09-1 μ-dinitrogenbis{dicarbonylbis(triethylphosphane)-iron} 
• 570-02-5 2,4,6-trimethoxybenzoic acid 

Relevant articles and documents

d8 Iron Nitrosylhydride Complexes

The nitrogen complex 2N2 (1) reacts with carboxylic acids to form the complexes (OC)2(Et3P)2Fe(H)OC(O)R .Treatment of 2 with N-methyl-N-nitroso-p-tolylsulfonamide produces the nitrosylcarboxylato complexes (OC)(ON)(Et3P)2FeOC(O)R (3a-d) in addition to the side product Fe(NO)2(PEt3)2 (4) except for 2e which forms 4 exclusively.Reaction of 3 with LiAlH4 yields the hydridonitrosyliron complex (OC)(ON)(Et3P)2FeH (5a).A different synthetic route to thephosphorus donor-substituted iron hydride complexes involves starting material (OC)2(L)2FeCl2 .Compounds 6 react with tBuLi and NOBF4 to form (OC)(ON)(L)2FeCl (7).Subsequent treatment with NaBH4 gives (OC)(ON)(L)2FeH .The structures of 5b and 7a are determined by X-ray crystallography.