1310329-52-2Relevant articles and documents
Gold-catalyzed regioselective oxidation ofterminal allenes: Formation of α-methanesulfonyloxy methyl ketones
Luo, Yingdong,Zhang, Guozhu,Hwang, Erik S.,Wilcoxon, Thomas A.,Zhang, Liming
supporting information; experimental part, p. 596 - 600 (2011/06/26)
Synthetically useful α-methanesulfonyloxy methyl ketones are readily prepared in one-step from terminal allenes in fair to good yields. The chemistry relies on a gold-catalyzed intermolecular oxidation of the 1,2-diene unit using 3,5-dichloropyridine N-ox