1310569-45-9Relevant articles and documents
Neighbouring formyl group assisted oxidation of o-alkynylarenecarbaldehydes by an iodine/water system
Sakthivel, Karuppusamy,Srinivasan, Kannupal
supporting information; experimental part, p. 2781 - 2784 (2011/06/23)
The oxidation of o-alkynylarenecarbaldehydes into tricarbonyl compounds by an iodine/water system is described. The reaction takes place via isochromenol intermediates formed by intramolecular assistance of the formyl group. The procedure was applied to various o-alkynylarenecarbaldehydes to afford the corresponding products in good to excellent yields.