131089-34-4

Basic information

• Product Name: 3-O-benzoyl-6-O-(t-butyldiphenyl)silyl-α-D-mannopyranoside
• Synonyms: 3-O-benzoyl-6-O-(t-butyldiphenyl)silyl-α-D-mannopyranoside
• CAS NO: 131089-34-4
• Molecular Weight: 432.589
• Mol File: 131089-34-4.mol
• Article Data: 17

Chemical Properties

• CAS DataBase Reference: 3-O-benzoyl-6-O-(t-butyldiphenyl)silyl-α-D-mannopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: 3-O-benzoyl-6-O-(t-butyldiphenyl)silyl-α-D-mannopyranoside(131089-34-4)
• EPA Substance Registry System: 3-O-benzoyl-6-O-(t-butyldiphenyl)silyl-α-D-mannopyranoside(131089-34-4)

Safety Data

• Hazardous Substances Data: 131089-34-4(Hazardous Substances Data)

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 617-04-9 (2R,3S,4S,5S,6S)-2-(hydroxymethyl)-6-methoxytetrahydro-2H-pyran-3,4,5-triol 
• 67-56-1 methanol 
• 87316-22-1 (2R,3S,4R)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-3,4-dihydro-2H-pyran-3,4-diol 

Downstream Products

• 1616283-80-7 methyl 6-O-tert-butyldiphenylsilyl-3-O-(3,4,6-tri-O-acetyl-2-deoxy-α-D-galactopyranosyl)-α-D-mannopyranoside 
• 1616283-63-6 methyl 6-O-tert-butyldiphenylsilyl-3-O-(3,4,6-tri-O-acetyl-2-deoxy-β-D-galactopyranosyl)-α-D-mannopyranoside 
• 1616283-56-7 methyl-6-O-tert-butyldiphenylsilyl-3-O-(3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranosyl)-α-D-mannopyranoside 
• 1616283-75-0 methyl-6-O-tert-butyldiphenylsilyl-3-O-(3,4,6-tri-O-acetyl-2-deoxy-α-D-glucopyranosyl)-α-D-mannopyranoside 
• 76251-67-7 methyl 3,4,6-tri-O-benzyl-α-D-mannopyranosyl-(1→6)-2,3,4-tri-O-benzyl-α-D-mannopyranoside 
• 15814-59-2 (2S,3S,4S,5S,6R)-2-methoxy-6-methyltetrahydro-2H-pyran-3,4,5-triol 
• 33639-74-6 methyl 2,3,4-tri-O-benzyl-α-D-rhamnopyranoside 
• 65518-53-8 methyl 2,3,4-tri-O-benzyl-6-O-tosyl-α-D-mannopyranoside 
• 131089-45-7 4-nitrophenyl O-(2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranosyl)-(1->2)-O-(3,6-di-O-acetyl-4-O-methyl-α-D-mannopyranosyl)-(1->6)-2,3-di-O-acetyl-β-D-glucopyranoside 
• 131089-40-2 methyl 2-O-(2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranosyl)-3,6-di-O-benzyl-4-O-methyl-α-D-mannopyranoside 
• 131089-46-8 4-nitrophenyl O-(2-acetamido-2-deoxy-β-D-glucopyranosyl)-(1->2)-O-(4-O-methyl-α-D-mannopyranosyl)-(1->6)-β-D-glucopyranoside 
• 131089-39-9 methyl 3,6-di-O-benzyl-4-O-methyl-α-D-mannopyranoside 
• 131089-37-7 methyl 6-O-benzyl-2,3-O-isopropylidene-4-O-methyl-α-D-mannopyranoside 
• 131089-38-8 methyl 6-O-benzyl-4-O-methyl-α-D-mannopyranoside 

Relevant articles and documents

Palladium-Catalyzed ortho-C-H Glycosylation/ ipso-Alkenylation of Aryl Iodides

This report describes the first example of palladium-catalyzed ortho-C-H glycosylation/ipso-alkenylation of aryl iodides, and the easily accessible glycosyl chlorides are used as a glycosylation reagent. The reaction is compatible with the functional groups of the substrates, and a series of C-aryl glycosides have been synthesized in good to excellent yield and with excellent diastereoselectivity. It is found that a cheap 5-norbornene-2-carbonitrile as a transient mediator can effectively promote this reaction. In addition, ipso-arylation and cyanation were also realized by the strategy.

One-pot synthesis of orthogonally protected sugars through sequential base-promoted/acid-catalyzed steps: A solvent-free approach with self-generation of a catalytic species

A varied set of solvent-free, one-pot synthetic sequences were developed to carry out the orthogonal protection of saccharide polyols. These sequences are composed of an initial regioselective benzylation, silylation or iodination (under mildly basic cond

Mannose-binding geometry of pradimicin A

Pradimicins (PRMs) and benanomicins are the only family of non-peptidic natural products with lectin-like properties, that is, they recognize D-mannopyranoside (Man) in the presence of Ca2+ ions. Coupled with their unique Man binding ability, t