13122-36-6Relevant articles and documents
A mild dehydrazination reaction of arylhydrazines using nitric oxide in the presence of oxygen
Matsuya, Yuji,Itoh, Takashi,Nagata, Kazuhiro,Ohsawa, Akio
, p. 15701 - 15710 (1997)
A new dehydrazination reaction of arylhydrazines using nitric oxide and oxygen as a mild nitrosating agent is described. Taking advantage of non-aqueous and non-acidic medium appears to cause this novel selectivity as a counterpart of the azide synthesis by the conventional methods. The generally and reaction mechanism were also investigated.
A preparing method of deuterated aromatic compounds
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Paragraph 0038; 0039, (2019/01/08)
The invention belongs to the field of chemical synthesis, particularly a preparing method of deuterated aromatic compounds. The method includes subjecting an aryl halide, as an initial raw material, to a palladium catalyzed carbon-halogen bond reduction r
Efficient Route to Deuterated Aromatics by the Deamination of Anilines
Burglova, Kristyna,Okorochenkov, Sergei,Hlavac, Jan
supporting information, p. 3342 - 3345 (2016/07/26)
One-step replacement of NH2 groups in ring-substituted anilines by deuterium is reported. Approaches comprising both solid-phase and solution-phase syntheses can be used on a large variety of substrates. The method uses diazotization in a mixture of water and either dichloromethane or chloroform, which serve as a source of hydrogen. This protocol can be used as a general method for fast and easy incorporation of deuterium into an aromatic system using deuterated chloroform.