131236-52-7

Basic information

• Product Name: 1-Methyl-4-(4-methylene-3-propyl-cyclohex-1-enylmethyl)-bicyclo[2.2.1]heptane
• Synonyms: 1-Methyl-4-(4-methylene-3-propyl-cyclohex-1-enylmethyl)-bicyclo[2.2.1]heptane
• CAS NO: 131236-52-7
• Molecular Weight: 258.447
• Mol File: 131236-52-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-Methyl-4-(4-methylene-3-propyl-cyclohex-1-enylmethyl)-bicyclo[2.2.1]heptane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Methyl-4-(4-methylene-3-propyl-cyclohex-1-enylmethyl)-bicyclo[2.2.1]heptane(131236-52-7)
• EPA Substance Registry System: 1-Methyl-4-(4-methylene-3-propyl-cyclohex-1-enylmethyl)-bicyclo[2.2.1]heptane(131236-52-7)

Safety Data

• Hazardous Substances Data: 131236-52-7(Hazardous Substances Data)

Upstream product

• 540-54-5 1-Chloropropane 
• 4982-20-1 1,4-dimethylidenecyclohexane 

Relevant articles and documents

Dianions of 1,4-Bis(methylene)cyclohexane. Conformational Effects in Cyclic and Acyclic Dilithiated Hydrocarbons

Dimetalation of 1,4-bis(methylene)cyclohexane results in formation of the p-xylene dianion via the linearly conjugated dianion 4.In contrast, 2-methyl-1,5-hexadiene, an acyclic analogue of 1,4-bis(methylene)cyclohexane, undergoes isomerization via the linearly conjugated dianion 12, rather than hydride elimination.MNDO calculations of the conformation of dilithiated 4 and 12 show that 4 is effectively planar, with a symmetrical distribution of charge.Dilithiated 12 is nonplanar, with an almost right angle bend in the ?-system.The dianion can therefore be considered as two allyl anions which are orthogonal to each other.The difference in calculated conformations of 4 and 12 is advanced as the reason for the different reactivity of the two systems.