131252-29-4Relevant articles and documents
Electroorganic Chemistry. 130. A Novel Trifluoromethylation of Aldehydes and Ketones Promoted by an Electrogenerated Base
Shono, Tatsuya,Ishifune, Manabu,Okada, Toshio,Kashimura, Shigenori
, p. 2 - 4 (1991)
A base generated by the electroreduction of 2-pyrrolidone deprotonated trifluoromethane to form a trifluoromethyl anion equivalent.In the presence of hexamethyldisilazane, this species reacted with a variety of aldehydes and ketones to afford (trifluoromethyl)-carbinols in high yield.