1312761-26-4

Basic information

• Product Name: 1-(anthracen-9-yl)ethyl isobutyrate
• CAS NO: 1312761-26-4
• Molecular Weight: 292.378
• Mol File: 1312761-26-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-(anthracen-9-yl)ethyl isobutyrate(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(anthracen-9-yl)ethyl isobutyrate(1312761-26-4)
• EPA Substance Registry System: 1-(anthracen-9-yl)ethyl isobutyrate(1312761-26-4)

Safety Data

• Hazardous Substances Data: 1312761-26-4(Hazardous Substances Data)

Upstream product

• 74928-67-9 9-(1-hydroxyethyl)anthracene 
• 97-72-3 2-Methylpropionic anhydride 

Relevant articles and documents

Kinetic resolution of secondary carbinols by a chiral N,N-4-dimethylaminopyridine derivative containing a 1,1′-binaphthyl unit: Hydrogen bonding affects catalytic activity and enantioselectivity

We developed an acylative kinetic resolution of secondary carbinols using a binaphthyl-based N,N-4-dimethylaminopyridine (DMAP) derivative 1d with tert-Alcohol substituents. The reaction proceeded with a wide range of carbinols with moderate to high selectivity (s) (up to s = 79.5). Kinetic studies revealed that catalyst 1d was more catalytically active than the corresponding bis-methyl ether 1d′ or DMAP. Hydrogen bonding between tert-Alcohols of the catalyst and secondary carbinols was responsible for the enhanced reaction rate and high enantioselectivity.