1312775-15-7Relevant articles and documents
Four-component radical-dual-difunctionalization (RDD) and decarbonylative alkylative peroxidation of two different alkenes with aliphatic aldehydes and TBHP
Liu, Ren-Xiang,Zhang, Feng,Peng, Yong,Yang, Luo
, p. 12080 - 12083 (2019)
From difunctionalization of a single alkene to radical-dual-difunctionalization of two different alkenes! Abundant aliphatic aldehydes were readily decarbonylated into alkyl radicals for the cascade construction of C(sp3)-C(sp3), C(sp3)-C(sp3) and C(sp3)-O bonds via double radical addition and radical-radical coupling, following the intrinsic nucleophilic/electrophilic reactivity of both the radicals and alkenes.
Iron-catalyzed carbonylation-peroxidation of alkenes with aldehydes and hydroperoxides
Liu, Weiping,Li, Yuanming,Liu, Kaisheng,Li, Zhiping
supporting information; experimental part, p. 10756 - 10759 (2011/08/22)
A three-component reaction of alkenes, aldehydes, and hydroperoxides catalyzed by FeCl2 to β-peroxy ketones has been achieved. This three-component reaction can be also applied to the synthesis of α-carbonyl epoxides, through either a stepwise base-induced epoxidation of the separated β-peroxy ketone products or a one-pot process by simply adding base to the reaction mixture after the completion of the three-component reaction.
