13131-19-6

Basic information

• Product Name: 10-methyl-1,4-dihydro-1,4-(epiminomethano)naphthalen-9-one
• Synonyms: N-Methyl-9-aza-tricyclo[6.2.2.0(2,7)]dodec-2,4,6,11-tetraene-10-one
• CAS NO: 13131-19-6
• Molecular Formula: C₁₂H₁₁NO
• Molecular Weight: 185.2218
• Mol File: 13131-19-6.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 358.8°C at 760 mmHg
• Flash Point: 147.4°C
• Density: 1.205g/cm³
• Vapor Pressure: 2.48E-05mmHg at 25°C
• Refractive Index: 1.616
• CAS DataBase Reference: 10-methyl-1,4-dihydro-1,4-(epiminomethano)naphthalen-9-one(CAS DataBase Reference)
• NIST Chemistry Reference: 10-methyl-1,4-dihydro-1,4-(epiminomethano)naphthalen-9-one(13131-19-6)
• EPA Substance Registry System: 10-methyl-1,4-dihydro-1,4-(epiminomethano)naphthalen-9-one(13131-19-6)

Safety Data

• Hazardous Substances Data: 13131-19-6(Hazardous Substances Data)

Usage

Molecular structure

A complex structure consisting of a naphthalene ring with a methyl and epiminomethano group attached.

Type of compound

Ketone, which means it contains a carbonyl group (C=O).

Synthesis

Can be synthesized in the laboratory.

Natural occurrence

Not commonly found in nature.

Potential applications

May have potential applications in organic chemistry, pharmaceuticals, or materials science due to its unique structure and properties.

Further research

Requires additional research and testing to determine its exact uses and potential benefits.

Upstream product

• 694-85-9 1-methyl-2-pyridone 
• 1608-42-0 benzenedizolium-2-carboxylate 
• 462-80-6 benzyne 
• 142-08-5 2-Pyridone 

Downstream Products

• 63385-90-0 2-methyl-5,6-benzo-2-azabicyclo<2.2.2>octane 

Relevant articles and documents

NMR Studies of N-Methyl Derivatives of the 2-Azabicycloheptyl and -octyl Ring System; Kinetic Protonation in Determination of Invertomer Preferences

The title compounds were studied by 1H, 13C, and 15N NMR spectroscopy.Since inversion at nitrogen is rapid on the NMR time scale even at low temperatures, kinetic protonation was used to estimate invertomer ratios at ambient temperature.Invertomer preferences appear to be consistent with the operation of steric factors.

DEILS-ALDER ADDUCTS FROM N-SUBSTTITUED TAUTOMERIC 2(1H)-PYRIDONE-2-HYDROXYPYRIDINES; 5,6-BENZO-AZABARRELENONES AND 5,6-BENZO-AZABARRELENES

Diels-Alder reactions of several N-unsubstitued tautomeric 2(1H)-pyridone-2-hydroxypyridines with benzyne were examined and found to afford 5,6-azabarrelenones, wich were converted to hitherto unknown 5,6-benzo-azabarrelenes.