131380-48-8

Basic information

• Product Name: 2-Butenal, 4-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (2E)-
• CAS NO: 131380-48-8
• Molecular Formula: C20H24O2Si
• Molecular Weight: 324.495
• Mol File: 131380-48-8.mol
• Article Data: 19

Chemical Properties

• CAS DataBase Reference: 2-Butenal, 4-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (2E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Butenal, 4-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (2E)-(131380-48-8)
• EPA Substance Registry System: 2-Butenal, 4-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (2E)-(131380-48-8)

Safety Data

• Hazardous Substances Data: 131380-48-8(Hazardous Substances Data)

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 92808-80-5 4-((tert-butyldiphenylsilyl)oxy)but-2-yn-1-ol 
• 87770-83-0 (Z)-4-((tert-butyldiphenylsilyl)oxy)but-2-en-1-ol 
• 92808-78-1 (E)-4-(tert-butyldiphenylsilyloxy)-2-buten-1-ol 

Downstream Products

• 92808-78-1 (E)-4-(tert-butyldiphenylsilyloxy)-2-buten-1-ol 
• 131380-44-4 (-)-lyxo-(4S,5S,6S)-7-(t-butyldiphenylsiloxy)-5,6-epoxy-4-(benzyloxy)hept-1-en-7-ol 
• 131484-40-7 ((2S,3S)-3-(((tert-butyldiphenylsilyl)oxy)methyl)oxiran-2-yl)methanol 
• 131486-44-7 (2R,3S)-3-(((tert-butyldiphenylsilyl)oxy)methyl)oxirane-2-carbaldehyde 
• 131484-24-7 (-)-xylo-(4R,5S,6S)-7-(tert-butyldiphenylsiloxy)-5,6-epoxyhept-1-en-4-ol 
• 131380-36-4 (-)-lyxo-(4S,5S,6S)-7-(tert-butyldiphenylsiloxy)-5,6-epoxyhept-1-en-4-ol 
• 131380-38-6 (-)-arabino-(4S,5S,6S)-7-(tert-butyldiphenylsiloxy)hept-1-ene-4,5,6-triol 4,5-carbonate 
• 131380-42-2 tert-Butyl-{(2S,3S)-3-[(S)-1-(1-ethoxy-ethoxy)-but-3-enyl]-oxiranylmethoxy}-diphenyl-silane 
• 131380-42-2 tert-Butyl-{(2S,3S)-3-[(R)-1-(1-ethoxy-ethoxy)-but-3-enyl]-oxiranylmethoxy}-diphenyl-silane 
• 131380-37-5 (-)-lyxo-(4S,5S,6S)-7-(tert-butyldiphenylsiloxy)-5,6-epoxy-4-<(phenylcarbamoyl)oxy>hept-1-ene 
• 455901-40-3 C₃₇H₆₃BO₅Si₃ 
• 610290-16-9 (2E-4-(tert-butyl-diphenyl-silanyloxy)-but-2-enoyl)-phosphonic acid dimethyl ester 
• 455901-41-4 (3S,15S,2R,13R,14R)(9Z,6E,11E,16E)-18-(2,2-dimethyl-1,1-diphenyl-1-silapropoxy)-10-bromo-N-methoxy-2,6,14-trimethyl-N-methyl-3,13,15-tris(1,1,2,2-tetramethyl-1-silapropoxy)octadeca-6,9,11,16-tetraenamide 
• 455901-51-6 C₃₇H₆₀O₃Si₃ 

Relevant articles and documents

Synthesis of (-)- and (+)-Gummiferol via Asymmetric Synthesis of Glycidic Amides

An efficient synthesis of the natural product (-)-gummiferol is achieved according to a novel asymmetric methodology of epoxide formation based on a new class of chiral sulfonium salts. This new methodology allows the rapid and efficient construction of t

Stereoselective synthesis of the C3-C15 fragment of callyspongiolide

The synthesis of C3-C15 fragment of callyspongiolide, a 14-membered macrolides isolated from the marine sponge Callyspongia sp., which was collected from the Indonesia, is reported. Highlights of the synthesis include construction of E-olefin through Juli

B(C6F5)3: A New Class of Strong and Bulky Lewis Acid for Exo-Selective Intermolecular Diels-Alder Reactions of Unreactive Acyclic Dienes with α,β-Enals

Lewis acid B(C6F5)3 catalyzed the Diels-Alder reactions of multisubstituted open-chain dienes and α,β-enals to afford the desired products with high exo-selectivities are reported. The substituent effect of the dienes and dienophiles on the products stereoselectivity was thoroughly investigated, and it was found that most of the desired exo-Diels-Alder products could be obtained in good yields and with high exo-stereoselectivities.