1313867-27-4

Basic information

• Product Name: 5-benzyloxy-2,5,5-trimethylpent-1-en-3-yne
• Synonyms: 5-benzyloxy-2,5,5-trimethylpent-1-en-3-yne
• CAS NO: 1313867-27-4
• Molecular Weight: 214.307
• Mol File: 1313867-27-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5-benzyloxy-2,5,5-trimethylpent-1-en-3-yne(CAS DataBase Reference)
• NIST Chemistry Reference: 5-benzyloxy-2,5,5-trimethylpent-1-en-3-yne(1313867-27-4)
• EPA Substance Registry System: 5-benzyloxy-2,5,5-trimethylpent-1-en-3-yne(1313867-27-4)

Safety Data

• Hazardous Substances Data: 1313867-27-4(Hazardous Substances Data)

Upstream product

• 78-80-8 2-methylbut-1-en-3-yne 
• 2696-26-6 2,5-dimethylhex-5-en-3-yn-2-ol 
• 100-39-0 benzyl bromide 

Downstream Products

• 1313867-49-0 3,3,4'-trimethyl-1'-tosyl-1',5'-dihydrospiro[isochroman-4,2'-pyrrole] 
• 1313867-36-5 2-(3-(benzyloxy)-3-methylbut-1-ynyl)-2-methyl-1-tosylaziridine 

Relevant articles and documents

Gold(i)-catalyzed rearrangement of aryl alkynylaziridines to spiro[isochroman-4,2′-pyrrolines]

Alkynylaziridines carrying an aryl group could be efficiently converted to spiro[isochroman-4,2′-pyrrolines] with gold salts as catalysts. This new rearrangement involved a Friedel-Crafts type intramolecular reaction followed by cyclization of the aminoallene intermediate, both initiated by the dual σ and π Lewis acidities of gold.