131387-86-5Relevant articles and documents
Regio- and stereoselective synthesis of tetrahydroindolysines, tetrahydropyridin-6-olates, and cyclopropanes from pyridinium ylides and unsaturated nitriles
Shestopalov,Litvinov,Rodinovskaya,Sharanin
, p. 129 - 138 (2007/10/02)
The regio- and stereoselectivity of the reactions of pyridinium ylides with unsaturated nitriles are dependent on the electronic nature of the substituent in position 3 of the pyridine ring. The reaction of 1-carbamoylmethylide-3-cyanopyridinium with aryl
THE CYCLIZATION REACTIONS OF NITRILES. XXXVI. THE REACTIONS OF FUNCTIONAL DERIVATIVES OF CYANOACETIC ACID WITH 1-STYRYLPYRIDINIUM SALTS AND THE STEREOCHEMISTRY OF THE FORMATION OF 4-ARYL-2-OXO-3-(1-PYRIDINO)-5-CYANO-3,4-TRANS-1,2,3,4-TETRAHYDRO-6-PYRIDINO
Shestopalov, A. M.,Sharanin, Yu. A.,Rodinovskaya, L. A.,Litvinov, V. P.
, p. 1356 - 1361 (2007/10/02)
The addition of cyanoacetic acid derivatives to 1-styrylpyridinium salts proceeds stereoselectively with the formation of anti-conformers of pyridinium 1,4-ylids, which also cyclize stereoselectively to give 4-aryl-2-oxo-3-(1-pyridino)-5-cyano-3,4-trans-1
