1314234-84-8

Basic information

• Product Name: 1-[(3,3-dimethylcycloprop-1-en-1-yl)methyl]-2-(prop-2-en-1-yloxy)benzene
• CAS NO: 1314234-84-8
• Molecular Weight: 214.307
• Mol File: 1314234-84-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-[(3,3-dimethylcycloprop-1-en-1-yl)methyl]-2-(prop-2-en-1-yloxy)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-[(3,3-dimethylcycloprop-1-en-1-yl)methyl]-2-(prop-2-en-1-yloxy)benzene(1314234-84-8)
• EPA Substance Registry System: 1-[(3,3-dimethylcycloprop-1-en-1-yl)methyl]-2-(prop-2-en-1-yloxy)benzene(1314234-84-8)

Safety Data

• Hazardous Substances Data: 1314234-84-8(Hazardous Substances Data)

Upstream product

• 23534-97-6 1,1,3‐tribromo‐2,2‐dimethylcyclopropane 
• 319918-15-5 1-(bromomethyl)-2-(prop-2-en-1-yloxy)benzene 
• 26906-01-4 2-allyloxybenzyl alcohol 

Relevant articles and documents

Rhodium-catalyzed cycloisomerization involving cyclopropenes: Efficient stereoselective synthesis of medium-sized heterocyclic scaffolds

A happy medium: The title reaction of cyclopropenyl carbinols and carbinylamines gives carbo- and heterocycles with a [6.1.0] bicyclic ring fused to an aromatic ring (see scheme, Alloc=allyloxycarbonyl, Boc=tert- butyloxycarbonyl). These reactions are the first examples of the formation of medium-sized rings by the intramolecular cyclopropanation of an alkene with a donor-substituted rhodium carbenoid, which is not generated from a diazo compound.