1314247-87-4

Basic information

• Product Name: 2-bromo-4-fluoro-1-(phenylethynyl)benzene
• Synonyms: 2-bromo-4-fluoro-1-(phenylethynyl)benzene
• CAS NO: 1314247-87-4
• Molecular Weight: 275.12
• Mol File: 1314247-87-4.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: 2-bromo-4-fluoro-1-(phenylethynyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-bromo-4-fluoro-1-(phenylethynyl)benzene(1314247-87-4)
• EPA Substance Registry System: 2-bromo-4-fluoro-1-(phenylethynyl)benzene(1314247-87-4)

Safety Data

• Hazardous Substances Data: 1314247-87-4(Hazardous Substances Data)

Upstream product

• 536-74-3 phenylacetylene 
• 202865-73-4 2-bromo-4-fluoro-1-iodobenzene 

Downstream Products

• 1618087-23-2 9-fluoro-5-methyl-6,11-diphenyl-5H-indeno[1,2-c]quinoline 
• 1131890-64-6 6-fluoro-1,2-diphenyl-1H-indole 
• 1429904-63-1 dimethyl 9-fluoro-6,11-diphenyl-5H-benzo[a]fluorene-5,5-dicarboxylate 
• 1401236-04-1 5′-fluoro-2′-(phenylethynyl)biphenyl-2-carbaldehyde 
• 1401236-18-7 (6-fluorophenanthrene-9-yl)(phenyl)methanone 
• 1388859-30-0 7-fluoro-1,1,3-triphenyl-1H-benzo[c][1,2]oxasiline 
• 1388859-17-3 (5-fluoro-2-(2-phenylethynyl)phenyl)diphenylsilanol 
• 1384966-41-9 6-fluoro-1-methyl-2-phenyl-1H-indole 
• 1384966-43-1 1-(2,6-diisopropyl-phenyl)-6-fluoro-2-phenyl-1H-indole 
• 1384966-42-0 1-adamantan-1-yl-6-fluoro-2-phenyl-1H-indole 
• 1326706-49-3 6-fluoro-2-phenylbenzo[b]thiophene 
• 1027976-96-0 5-fluoro-2-phenylethynylphenylamine 
• 255724-72-2 6-fluoro-2-phenyl-1H-indole 

Relevant articles and documents

Sequential Addition of Amines to Nitrile and Carbon-Carbon Multiple Bond: A Route to 7-Amino-5 H-dibenzo[ c,e]azepines

A rare earth metal-catalyzed sequential inter- and intramolecular C-N bond formation of 2-nitrile-2′-alkenyl(alkynyl)biphenyls with amines has been developed, which provides a straightforward and efficient access to a range of new functional dibenzo[c,e]azepines. This represents the first examples of direct construction of seven-membered azaheterocycle from unsaturated nitriles and amines. Such transformations have the advantages of avoiding the use of additives, easily available starting materials, step- and high atom-economy, mild reaction conditions, and high selectivity.

Synthesis of Naphthalenyl Triflates via the Cationic Annulation of Benzodiynes with Triflic Acid

A highly efficient and regioselective annulation of benzodiynes promoted by triflic acid has been developed. This protocol provides a step and atom-economic access to a series of naphthalenyl triflates. Furthermore, direct synthetic applications of this r

Construction of Six-Membered Silacyclic Skeletons via Platinum-Catalyzed Tandem Hydrosilylation/Cyclization with Dihydrosilanes

Catalytic silicon-carbon or silicon-heteroatom bond-forming hydrosilylation has become increasingly important in synthetic chemistry, catalysis and organosilicon chemistry. Herein we report a platinum-catalyzed one-pot and tandem hydrosilylation/cyclization of OH-containing alkynes with dihydrosilanes, allowing for facile synthesis of six-membered organosilicon compounds, including silyloxycycles and cyclic siloxanes in high yields and with good stereoselectivities. (Figure presented.).