131458-55-4

Basic information

• Product Name: meta-ethynyl-(4,4,5,5-tetramethyl-4,5-dihydro-1H-3-(N-oxide)-imidazol-1-yloxyl)-phenyl
• Synonyms: meta-ethynyl-(4,4,5,5-tetramethyl-4,5-dihydro-1H-3-(N-oxide)-imidazol-1-yloxyl)-phenyl
• CAS NO: 131458-55-4
• Molecular Weight: 257.312
• Mol File: 131458-55-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: meta-ethynyl-(4,4,5,5-tetramethyl-4,5-dihydro-1H-3-(N-oxide)-imidazol-1-yloxyl)-phenyl(CAS DataBase Reference)
• NIST Chemistry Reference: meta-ethynyl-(4,4,5,5-tetramethyl-4,5-dihydro-1H-3-(N-oxide)-imidazol-1-yloxyl)-phenyl(131458-55-4)
• EPA Substance Registry System: meta-ethynyl-(4,4,5,5-tetramethyl-4,5-dihydro-1H-3-(N-oxide)-imidazol-1-yloxyl)-phenyl(131458-55-4)

Safety Data

• Hazardous Substances Data: 131458-55-4(Hazardous Substances Data)

Upstream product

• 208943-28-6 4-[3-(hydroxymethyl)phenyl]-2-methylbut-3-yn-2-ol 
• 77123-56-9 3-ethynylbenzaldehyde 
• 10602-07-0 3-(hydroxymethyl)ethynylbenzene 
• 696-41-3 m-iodobenzaldehyde 
• 158520-43-5 1,3-dihydroxy-2-(3-ethynylphenyl)-4,4,5,5-tetramethylimidazolidine 
• 95785-27-6 3-(3-hydroxy-3-methylbut-1-yn-1-yl)benzaldehyde 

Downstream Products

• 791823-93-3 trans[bis(meta-ethynyl-(4,4,5,5-tetramethyl-4,5-dihydro-1H-3-(N-oxide)-imidazol-1-yloxyl)-phenyl)bis(triphenylphosphine)platinum(II)] 

Relevant articles and documents

Cross-coupling of aryl iodides with paramagnetic terminal acetylenes derived from 4,4,5,5-tetramethyl-2-imidazoline-2-oxyl 3-oxide

2-(Arylylethynylphenyl)-4,4,5,5-tetramethyl-2-imidazoline-1-oxyl 3-oxides 12 and 13 were synthesized by cross-coupling of aryl iodides with 1-alkynes containing the 4,4,5,5-tetramethyl-2-imidazoline-1-oxyl 3-oxide fragment. A procedure was developed for the preparation of 3-and 4-ethynyibenzaldehydes with the use of 2-methylbut-3-yn-2-ol.