13146-08-2

Basic information

• Product Name: Toluol-4-sulfinsaeure-neopentylester
• CAS NO: 13146-08-2
• Molecular Weight: 226.34
• Mol File: 13146-08-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Toluol-4-sulfinsaeure-neopentylester(CAS DataBase Reference)
• NIST Chemistry Reference: Toluol-4-sulfinsaeure-neopentylester(13146-08-2)
• EPA Substance Registry System: Toluol-4-sulfinsaeure-neopentylester(13146-08-2)

Safety Data

• Hazardous Substances Data: 13146-08-2(Hazardous Substances Data)

Upstream product

• 10439-23-3 4-methylbenzenesulfinyl chloride 
• 75-84-3 2,2-dimethyl-propanol-1 

Downstream Products

• 49833-45-6 tert-butyl 4-methylphenyl sulfoxide 

Relevant articles and documents

ORGANOSULPHUR COMPOUNDS-LXIX OPTICALLY ACTIVE SULPHINATES: A NEW TYPE OF ENANTIOSELECTIVE ASYMMETRIC SYNTHESIS AND KINETIC RESOLUTION

Optically active sulphinates with the sulphur atom as a sole centre of chirality are prepared by two methods.The first involves the reaction of symmetrical sulphites with tert-butylmagnesium chloride in the presence of optically active aminoalcohols.This new asymmetric, enantioselective synthesis affords t-butylsulphinates with 40-70percent enantiomeric excess values.The second approach is based on a new type of kinetic resolution taking place when racemic sulphinates are reacted with tert-butylmagnesium chloride complexed by optically active alkaloid bases.Both the recovered sulphinates and sulphoxides formed in this reaction show moderate optical purities.