131506-90-6Relevant articles and documents
Selective Oxidation of Phosphorus Ylides by Dimethyldioxirane. Application to the Formation of Vicinal Tricarbonyls
Wasserman, Harry H.,Baldino, Carmen M.,Coats, Steven J.
, p. 8231 - 8235 (1995)
Dimethyldioxirane (DMD) has proven to be an effective reagent for the selective conversion of phosphoranylidene intermediates 4 to the corresponding vicinal tricarbonyls 5.Unlike existing oxidation protocols which employ relatively vigorous conditions, th