1315614-14-2

Basic information

• Product Name: N-(2-((5aS,9aR)-1-((1,3-dioxolan-2-yl)methyl)-4-methoxy-6-oxo-5a,6,7,9a-tetrahydrodibenzo[b,d]furan-9a-yl)ethyl)-N-methyl-2,4-dinitrobenzenesulfonamide
• CAS NO: 1315614-14-2
• Molecular Weight: 589.58
• Mol File: 1315614-14-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-(2-((5aS,9aR)-1-((1,3-dioxolan-2-yl)methyl)-4-methoxy-6-oxo-5a,6,7,9a-tetrahydrodibenzo[b,d]furan-9a-yl)ethyl)-N-methyl-2,4-dinitrobenzenesulfonamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(2-((5aS,9aR)-1-((1,3-dioxolan-2-yl)methyl)-4-methoxy-6-oxo-5a,6,7,9a-tetrahydrodibenzo[b,d]furan-9a-yl)ethyl)-N-methyl-2,4-dinitrobenzenesulfonamide(1315614-14-2)
• EPA Substance Registry System: N-(2-((5aS,9aR)-1-((1,3-dioxolan-2-yl)methyl)-4-methoxy-6-oxo-5a,6,7,9a-tetrahydrodibenzo[b,d]furan-9a-yl)ethyl)-N-methyl-2,4-dinitrobenzenesulfonamide(1315614-14-2)

Safety Data

• Hazardous Substances Data: 1315614-14-2(Hazardous Substances Data)

Upstream product

• 164021-77-6 (5S,6R)-1-(2-bromoethyl)cyclohexa-1,3-dien-5,6-diol 
• 164021-78-7 (1S,2R)-3-(2-bromoethyl)cyclohex-5-ene-1,2-diol 
• 103-63-9 1-phenyl-2-bromoethane 
• 115961-42-7 2-bromo-3-(methoxymethoxy)-4-methoxybenzaldehyde 
• 1656-44-6 2,4-dinitrobenzenesulfonyl chloride 
• 1315613-94-5 C₁₁H₁₇BrO₂ 
• 1315613-93-4 2-bromo-3-(1,3-dioxolan-2-ylmethyl)-6-methoxyphenol 
• 1315613-92-3 C₁₂H₁₅BrO₄ 
• 1315614-13-1 N-(2-((5aS,6S,9aR)-1-((1,3-dioxolan-2-yl)methyl)-6-hydroxy-4-methoxy-5a,6,7,9a-tetrahydrodibenzo[b,d]furan-9a-yl)ethyl)-N-methyl-2,4-dinitrobenzenesulfonamide 
• 1315614-04-0 (4S,4aS,9bR)-9-((1,3-dioxolan-2-yl)methyl)-6-methoxy-9b-(2-(methylamino)ethyl)-3,4,4a,9b-tetrahydrodibenzo[b,d]furan-4-ol 
• 1315613-99-0 tert-butyl 2-((5aS,6S,9aR)-1-((1,3-dioxolan-2-yl)methyl)-6-hydroxy-4-methoxy-5a,6,7,9a tetrahydrodibenzo[b,d]furan-9a-yl)ethyl(methyl)carbamate 
• 1315613-96-7 tert-butyl 2-((5'S,6'S)-6'-(3''-((1,3-dioxolan-2-yl)methyl)-2''-bromo-6''-methoxyphenoxy)-5'-(tert-butyldimethylsilyloxy)cyclohex-1'-enyl)ethyl(methyl)carbamate 
• 621-59-0 isovanillin 

Downstream Products

• 1315614-15-3 (2a⁽²⁾R,6aS,9aS)-5-Methoxy-2a2-(2-(N-methyl-2,4-dinitrophenylsulfonamido)ethyl)-7-oxo-1,2,2a⁽²⁾,6a,7,9a-hexahydrophenanthro[4,5-bcd]furan-1-yl methanesulfonate 
• 1315614-16-4 N-(2-((2a⁽¹⁾R,5aS)-7-methoxy-5-oxo-1,2a1,5,5a-tetrahydrophenanthro[4,5-bcd]furan-2a1-yl)ethyl)-N-methyl-2,4-dinitrobenzenesulfonamide 
• 1315614-17-5 N-(2-((2a1R,5aS)-7-methoxy-5-oxo-2a1,4,5,5a-tetrahydrophenanthro[4,5-bcd]furan-2a1-yl)ethyl)-N-methyl-2,4-dinitrobenzenesulfonamide 

Relevant articles and documents

Chemoenzymatic total synthesis of ent-neopinone and formal total synthesis of ent -codeinone from β-bromoethylbenzene

Formal total synthesis of ent-codeinone and ent-codeine was accomplished via the total synthesis of ent-neopinone attained in 14 steps from β-bromoethylbenzene. The key steps included (i) enzymatic dihydroxylation of β-bromoethylbenzene with E. coli JM109