1316054-11-1

Basic information

• Product Name: (E)-4,5-dichloro-2-[(2-hydroxy-3-nitrocyclohex-2-en-1-yliden)methyl]benzaldehyde
• Synonyms: (E)-4,5-dichloro-2-[(2-hydroxy-3-nitrocyclohex-2-en-1-yliden)methyl]benzaldehyde
• CAS NO: 1316054-11-1
• Molecular Weight: 328.152
• Mol File: 1316054-11-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-4,5-dichloro-2-[(2-hydroxy-3-nitrocyclohex-2-en-1-yliden)methyl]benzaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-4,5-dichloro-2-[(2-hydroxy-3-nitrocyclohex-2-en-1-yliden)methyl]benzaldehyde(1316054-11-1)
• EPA Substance Registry System: (E)-4,5-dichloro-2-[(2-hydroxy-3-nitrocyclohex-2-en-1-yliden)methyl]benzaldehyde(1316054-11-1)

Safety Data

• Hazardous Substances Data: 1316054-11-1(Hazardous Substances Data)

Upstream product

• 24006-92-6 4,5-dichlorobenzene-1,2-dimethanol 
• 4883-67-4 2-nitrocyclohexanone 
• 13209-33-1 4,5-dichlorobenzene-1,2-dicarbaldehyde 

Relevant articles and documents

Two chemodivergent anionic domino processes from cyclic α-nitroketones and aromatic aldehydes

Treatment of cyclic α-nitroketones and aromatic 1,2-dialdehydes with DBU in tetrahydrofuran containing small amounts of water proceeded through two chemodivergent one-pot domino pathways, whose outcome depended on the ring size of the starting nitroketone. Thus, α-nitrocyclohexanone underwent diastereoselective α′-arylmethylenation reactions through a nitroaldol/aldol/reverse nitroaldol mechanism. On the other hand, α-nitrocycloheptanone and α-nitrocyclooctanone afforded 2-nitroindane-1,2-diols containing three contiguous stereocenters in a highly diastereoselective fashion through a nitroaldol/retro-Dieckmann/intramolecular nitroaldol process.