131613-80-4

Basic information

• Product Name: methyl 4,6-O-benzylidene-3-chloro-3-deoxy-α-D-altroside
• CAS NO: 131613-80-4
• Molecular Weight: 300.739
• Mol File: 131613-80-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl 4,6-O-benzylidene-3-chloro-3-deoxy-α-D-altroside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 4,6-O-benzylidene-3-chloro-3-deoxy-α-D-altroside(131613-80-4)
• EPA Substance Registry System: methyl 4,6-O-benzylidene-3-chloro-3-deoxy-α-D-altroside(131613-80-4)

Safety Data

• Hazardous Substances Data: 131613-80-4(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 87668-69-7 methyl-(3-chloro-3-deoxy-α-D-altropyranoside) 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 65556-00-5 methyl 4,6-di-O-benzylidene-2,3-di-O-tosyl-α-D-glucopyranoside 
• 2622-05-1 allylmagnesium bromide 
• 3150-15-0 methyl 2,3-anhydro-4,6-O-benzilidene-α-D-mannopyranoside 
• 5674-01-1 2-methylallylmagnesium chloride 
• 66537-92-6 methyl 2,3-anhydro-4,6-benzylidene-α-D-allopyranoside 

Relevant articles and documents

Aldotetroses and C(3)-Modified Aldohexoses as Substrates for N-Acetylneuraminic Acid Aldolase: A Model for the Explanation of the Normal and the Inversed Stereoselectivity

The four stereoisomeric aldotetroses were accepted with different reactivities by N-acetylneuraminic acid aldolase.C(3)-modified D-mannose and D-glucose derivatives, respectively, failed to undergo enzymatic aldol addition.Based on the observed reactivities of the tested compounds (about 58), a mechanistic scheme is proposed which relates substrate structure, reactivity and stereochemical outcome observed in Neu5Ac aldolase-catalyzed reactions.The condensation products obtained in the L-erythrose and D-threose reactions are side-chain modified sialic acid and D-KDO derivatives, respectively, of biological interest.