131699-30-4

Basic information

• Product Name: 1,1-Diphenyl-2-phenylamino-2-phenylethanol
• Synonyms: 1,1-Diphenyl-2-phenylamino-2-phenylethanol
• CAS NO: 131699-30-4
• Molecular Weight: 365.475
• Mol File: 131699-30-4.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1,1-Diphenyl-2-phenylamino-2-phenylethanol(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1-Diphenyl-2-phenylamino-2-phenylethanol(131699-30-4)
• EPA Substance Registry System: 1,1-Diphenyl-2-phenylamino-2-phenylethanol(131699-30-4)

Safety Data

• Hazardous Substances Data: 131699-30-4(Hazardous Substances Data)

Upstream product

• 5722-91-8 1,2-diphenyl-2-(phenylamino)ethanone 
• 119-61-9 benzophenone 
• 142943-95-1 α,N-Diphenyl-1H-benzotriazole-1-methanamine 
• 538-51-2 benzylidene phenylamine 

Downstream Products

• 1733-63-7 1,2,2-triphenylethan-1-one 

Relevant articles and documents

Reductive coupling of ketones with imines promoted by the titanium tetrachloride/samarium system

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Titanium-mediated cross-coupling reactions of imines with ketones or aldehydes: An efficient route for the synthesis of 1,2-amino alcohols

The cross-coupling reactions of imines with ketones using Ti(O iPr)4/c-C5H9MgCl reagent lead to 1,2-amino alcohols after hydrolysis. The coupling reactions with aldehydes could also afford 1,2-amino alcohols, however, in some cases, aziridines were obtained as major products in a stereoselective manner.

Samarium (ii) iodide promoted reductive coupling of ketones and imines

The cross-coupling reactions of imines with aromatic ketones induced by Sml2/THF system were studied; 2-amino alcohols are prepared in good yields under refluxing conditions.