13177-56-5

Basic information

• Product Name: 9-deuteriofluorene
• Synonyms: 9-deuteriofluorene
• CAS NO: 13177-56-5
• Molecular Weight: 167.214
• Mol File: 13177-56-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 9-deuteriofluorene(CAS DataBase Reference)
• NIST Chemistry Reference: 9-deuteriofluorene(13177-56-5)
• EPA Substance Registry System: 9-deuteriofluorene(13177-56-5)

Safety Data

• Hazardous Substances Data: 13177-56-5(Hazardous Substances Data)

Upstream product

• 88655-95-2 9-(Trideuteriomethoxy)fluorene 
• 7385-10-6 9-(trimethylsilyl)fluorene 
• 86-73-7 9H-fluorene 
• 26138-28-3 phenylytterbium iodide 

Relevant articles and documents

Contrasting Photosolvolytic Reactivities of 9-Fluorenol vs 5-Suberenol Derivatives. Enhanced Rate of Formation of Cyclically Conjugated Four ? Carbocations in the Excited State

The photosolvolysis of 9-fluorenol (1) and several of its derivatives, as well as related systems, has been studied in aqueous methanol and acetonitrile solutions.The primary aim of this study was to examine the effect of the internal cyclic array (ICA) of these compounds in promoting photosolvolysis with respect to the number of ? electrons available in the ICA.It was observed that 9-fluorenol derivatives photosolvolyze much more efficiently than any of the related systems studied in this work.In contrast, ground-state 9-fluorenol derivatives are the least reactive systems with respect to solvolysis.Quantum yields for methyl ether formation for photosolvolysis in 50percent MeOH-H2O are reported for 1-3.Rate constants for solvent-assisted photodehydroxylation (ks) are calculated on the basis of the proposed mechanism of heterolytic C-OH bond rupture in the primary photochemical step and are in the range (1.3-1.6)x1E10 s-1 for 1-3.

ORGANIC DERIVATIVES OF DIVALENT YTTERBIUM RYbX IN METALLATION RECTIONS

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