13181-29-8

Basic information

• Product Name: 2-Hexanone, 5-methyl-, O-(2,4-dinitrophenyl)oxime
• CAS NO: 13181-29-8
• Molecular Formula: C13H17N3O5
• Molecular Weight: 295.295
• Mol File: 13181-29-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-Hexanone, 5-methyl-, O-(2,4-dinitrophenyl)oxime(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Hexanone, 5-methyl-, O-(2,4-dinitrophenyl)oxime(13181-29-8)
• EPA Substance Registry System: 2-Hexanone, 5-methyl-, O-(2,4-dinitrophenyl)oxime(13181-29-8)

Safety Data

• Hazardous Substances Data: 13181-29-8(Hazardous Substances Data)

Upstream product

• 4548-78-1 (3-methylbutyl)magnesium bromide 
• 110-12-3 5-Methyl-2-hexanone 
• 624-44-2 5-methyl-hexan-2-one oxime 
• 97-00-7 1-chloro-2,4-dinitro-benzene 

Relevant articles and documents

Iminyl Radical-Mediated Controlled Hydroxyalkylation of Remote C(sp3)-H Bond via Tandem 1,5-HAT and Difunctionalization of Aryl Alkenes

A visible-light mediated γ-hydroxyalkylation of ketones via C(sp3)-H functionalization has been developed under redox neutral conditions. This protocol relies on the iminyl radical-triggered 1,5-HAT followed by oxyalkylation of alkenes, wherein C?C and C?O bonds were constructed in one step. This three-component reaction features mild conditions, wide substrate scope and excellent functional group tolerance, thus providing a facile and highly efficient access to complex valuable ketones. (Figure presented.).