131846-31-6

Basic information

• Product Name: methyl (±)-anti-2-iodo-3-methoxy-3-phenylpropanoate
• CAS NO: 131846-31-6
• Molecular Weight: 320.127
• Mol File: 131846-31-6.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: methyl (±)-anti-2-iodo-3-methoxy-3-phenylpropanoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (±)-anti-2-iodo-3-methoxy-3-phenylpropanoate(131846-31-6)
• EPA Substance Registry System: methyl (±)-anti-2-iodo-3-methoxy-3-phenylpropanoate(131846-31-6)

Safety Data

• Hazardous Substances Data: 131846-31-6(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 621-82-9 Cinnamic acid 
• 103-26-4 Methyl cinnamate 
• 103-26-4 methyl cinnamate 
• 140-10-3 (E)-3-phenylacrylic acid 
• 87207-03-2 methyl β-chloro-α-iodo-β-phenylpropionate 
• 7790-99-0 Iodine monochloride 

Downstream Products

• 133379-85-8 methyl (2R*,3R*)-2--3-methoxy-3-phenylpropanoate 
• 133379-85-8 methyl (2S*,3R*)-2--3-methoxy-3-phenylpropanoate 

Relevant articles and documents

A new alkoxy-, hydroxy-and nitratoiodination of a,β-unsaturated esters and amides using iodine-ammonium cerium (IV) nitrate and cerium (IV) sulfate

The reactions of electron-deficient α β-unsaturated esters using I2-ammonium cerium (IV) nitrate (CAN) or I2-cerium (IV) sulfate (CS) in alcohols (methanol, ethanol, or 1-propanol) under 50°C-reflux give the corresponding-β-alkoxy-a-

Stereoselective radical carbon-carbon bond forming reactions of β-alkoxy esters: Atom and group transfer allylations under bidentate chelation controlled conditions

The radical allylation of a series of β-alkoxy esters using allyltrimethylsilane in the presence of MgBr2·OEt2 is described. Under bidentate chelation-controlled conditions, allyltrimethylsilane rivals allyltributyltin in efficiency

Metal Reagents in Organic Reactions: Part IV-Mercuration and Demercuration of Cinnamic Acid and Its Derivatives

Methoxy-mercuration of cinnamic acid and methyl cinnamate with mercuric acetate in dry methanol has been carried out and the products identified.Transformation reactions of the mercurated products have been investigated, particularly regarding their behav