131896-99-6

Basic information

• Product Name: methyl 2,3,5-tri-O-benzyl-α-L-ribofuranoside
• Synonyms: methyl 2,3,5-tri-O-benzyl-α-L-ribofuranoside
• CAS NO: 131896-99-6
• Molecular Weight: 434.532
• Mol File: 131896-99-6.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: methyl 2,3,5-tri-O-benzyl-α-L-ribofuranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2,3,5-tri-O-benzyl-α-L-ribofuranoside(131896-99-6)
• EPA Substance Registry System: methyl 2,3,5-tri-O-benzyl-α-L-ribofuranoside(131896-99-6)

Safety Data

• Hazardous Substances Data: 131896-99-6(Hazardous Substances Data)

Upstream product

• 67737-48-8 methyl 5-benzyloxy-β-D-ribofuranoside 
• 100-44-7 benzyl chloride 
• 67-56-1 methanol 
• 41546-21-8 L-ribose 
• 100-39-0 benzyl bromide 
• 52689-55-1 methyl α-L-ribofuranoside 
• 1824-96-0 methyl ribofuranoside 
• 86883-41-2 2,3,5-tri-O-benzyl-α-D-ribofuranosyl fluoride 
• 33019-63-5 (2R,3R,4R,5R)-2-benzyloxymethyl-3,4-isopropylidenedioxy-5-methoxytetrahydrofuran 
• 191543-71-2 methyl 3,5-di-O-benzyl-α-D-ribofuranoside 
• 16838-89-4 2,3,5-tri-O-benzyl-D-ribofuranose 
• 4356-80-3 methyl 2,3,4-tri-O-benzyl-β-D-glucopyranoside 
• 1825-61-2 Trimethylmethoxysilane 
• 96-36-6 methyl phosphite 

Downstream Products

• 131771-55-6 1,3,4-tri-O-benzyl-2-O-<2-O-(benzyloxymethyl)-5-O-(dimethoxytrityl)-β-D-ribofuranosyl>-5-O-(dimethoxytrityl)-D-ribitol 
• 131771-53-4 1,3,4-tri-O-benzyl-2-O-<2-O-(benzyloxymethyl)-5-O-4,4'-dimethoxytrityl-β-D-ribofuranosyl>-5-O-pivaloyl-D-ribitol 
• 131771-48-7 2-O-(2,3,5-tri-O-benzoyl-β-D-ribofuranosyl)-1,3,4-tri-O-benzyl-5-O-pivaloyl-D-ribitol 
• 131771-54-5 1,3,4-tri-O-benzyl-2-O-<2-O-(benzyloxymethyl)-5-O-(dimethoxytrityl)-β-D-ribofuranosyl>-D-ribitol 
• 131771-51-2 1,3,4-tri-O-benzyl-5-O-pivaloyl-2-O-<2-O-(benzyloxymethyl)-3,5-O-(tetraisopropyldisiloxane-1,3-diyl)-β-D-ribofuranosyl>-D-ribitol 
• 131771-50-1 1,3,4-tri-O-benzyl-5-O-pivaloyl-2-O-<3,5-O-(tetraisopropyldisiloxane-1,3-diyl)-β-D-ribofuranosyl>-D-ribitol 
• 131771-52-3 1,3,4-tri-O-benzyl-2-O-<2-O-(benzyloxymethyl)-β-D-ribofuranosyl>-5-O-pivaloyl-D-ribitol 
• 131771-49-8 1,3,4-tri-O-benzyl-5-O-pivaloyl-2-O-(β-D-ribofuranosyl)-D-ribitol 
• 122501-70-6 1,3,4-tri-O-benzyl-5-O-pivaloyl-D-ribitol 
• 131897-00-2 1,3,4-tri-O-benzyl-D-ribitol 
• 16838-89-4 2,3,5-tri-O-benzyl-α-L-ribofuranose 
• 1428321-46-3 (1R,2R,3R,4R)-2,3,5-tris(benzyloxy)-1-methoxy-1-(phenylthio)pentan-4-ol 
• 93836-22-7 4,7-anhydro-5,6,8-tri-O-benzyl-1,2,3-trideoxy-D-altro-oct-1-enitol 
• 1330085-36-3 3-(2,3,5-tri-O-benzyl-α-D-ribofuranosyl)-1-propyne 

Relevant articles and documents

Synthesis of 1,2-cis -homoiminosugars derived from GlcNAc and GaLNAc exploiting a β-amino alcohol skeletal rearrangement

The synthesis of 1,2-cis-homoiminosugars bearing an NHAc group at the C-2 position is described. The key step to prepare these α-d-GlcNAc and α-d-GalNAc mimics utilizes a β-amino alcohol skeletal rearrangement applied to an azepane precursor. This strateg

Synthesis and properties of triplex-forming oligonucleotides containing 2′-O-(2-methoxyethyl)-5-(3-aminoprop-1-ynyl)-uridine

2′-O-(2-Methoxyethyl)-5-(3-aminoprop-1-ynyl)-uridine phosphoramidite (MEPU) has been synthesized from d-ribose and 5-iodouracil and incorporated into triplex-forming oligonucleotides (TFOs) by automated solid-phase oligonucleotide synthesis. The TFOs gave very high triplex stability with their target duplexes as measured by ultraviolet/fluorescence melting and DNase I footprinting. The incorporation of MEPU into TFOs renders them resistant to degradation by serum nucleases.

Stereoselective syntheses of α-D- and β-D-ribofuranosides catalyzed by the combined use of silver salts and their partners

α-D-Ribofuranosides are stereoselectively synthesized in high yields from 2,3,5-tri-O-benzyl-1-O-iodoacetyl-D-ribofuranose (1) and trimethylsilylated nucleophiles by the use of silver salts in the coexistence of 3 molar amounts of lithium perchlorate, whi