13206-64-9Relevant articles and documents
Alkyl coupling in tertiary amines as analog of Guerbet condensation reaction
Zhou, Yage,Wu, Dan,Hernández, Willinton Yesid,Ma, Changru,Su, Huangyang,Ordomsky, Vitaly
, p. 9845 - 9849 (2019/04/01)
We report here that C-C coupling in tertiary amines for the synthesis of long chain and hindered amines might be efficiently performed over Pt and Pd catalysts. The mechanism study confirms similarity with the Guerbet reaction through dehydrogenation of the alkyl group and subsequent attack of the α-carbon atom by an alkyl group of another molecule. Finally, secondary amines and tertiary amines with longer alkyl chains are formed.
Electrophilic Amination with Nitroarenes
Rauser, Marian,Ascheberg, Christoph,Niggemann, Meike
supporting information, p. 11570 - 11574 (2017/09/11)
An exceptionally general electrophilic amination, which directly transforms commercially available nitroarenes into alkylated aromatic aminoboranes with zinc organyl compounds was developed. The reaction starts with a two-step partial reduction of the nitro group to a nitrenoid, which is used in situ as the electrophilic amination reagent. To facilitate isolation, the resulting air- and moisture-sensitive aminoboranes were reacted with a range of electrophiles. The method not only represents a direct transformation of nitro compounds into electrophilic amination reagents but also provides an elegant alternative to dehydrocoupling methods for the generation of aminoboranes.
Synthesis of Amines by the Intermolecular Schmidt Reaction of Aliphatic Azides with Carbocations
Pearson, William H.,Fang, Wen-kui
, p. 4960 - 4961 (2007/10/02)
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