132157-39-2Relevant articles and documents
Chiral Organometallic Reagents, I. Stereoselective Exchange of Diastereotopic Bromine Atoms by Lithium in 1,1-Dibromo-3-(trimethylsilyloxy)alkanes
Hoffmann, Reinhard W.,Bewersdorf, Martin,Krueger, Michael,Mikolaiski, Wolfgang,Stuermer, Rainer
, p. 1243 - 1252 (2007/10/02)
Bromine-lithium exchange in 1,1-dibromo-3-(trimethylsilyloxy)alkanes 4 and 6 affords the carbenoids 8 and 14, which have been added to ketones, aldehydes, arylboronates, and silylating agents.Diastereoselectivity in the generation and trapping of the carb