1321591-62-1Relevant articles and documents
Direct substitution of the hydroxy group with highly functionalized nitrogen nucleophiles catalyzed by Au(III)
Ohshima, Takashi,Nakahara, Yasuhito,Ipposhi, Junji,Miyamoto, Yoshiki,Mashima, Kazushi
supporting information; experimental part, p. 8322 - 8324 (2011/09/15)
A direct catalytic substitution of various allylic and benzylic alcohols with synthetically useful, but acid-sensitive Boc, Bus, and Dios protected amine nucleophiles, which have not been well utilized for Lewis acid catalysis, with various functionalities (OTBS, OTHP, etc.) was efficiently catalyzed by 1 mol% of Au(iii) under mild conditions.