132205-06-2

Basic information

• Product Name: (1Z,3R*)-3-(tert-Butyldiphenylsilyloxy)-1-iodo-1-butene
• Synonyms: (1Z,3R*)-3-(tert-Butyldiphenylsilyloxy)-1-iodo-1-butene
• CAS NO: 132205-06-2
• Molecular Weight: 436.408
• Mol File: 132205-06-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1Z,3R*)-3-(tert-Butyldiphenylsilyloxy)-1-iodo-1-butene(CAS DataBase Reference)
• NIST Chemistry Reference: (1Z,3R*)-3-(tert-Butyldiphenylsilyloxy)-1-iodo-1-butene(132205-06-2)
• EPA Substance Registry System: (1Z,3R*)-3-(tert-Butyldiphenylsilyloxy)-1-iodo-1-butene(132205-06-2)

Safety Data

• Hazardous Substances Data: 132205-06-2(Hazardous Substances Data)

Upstream product

• 74785-04-9 (2R*,3Z)-4-Iodo-3-buten-2-ol 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Downstream Products

• 132205-07-3 (1R*,2Z,3S*)/(1R*,2Z,3R*)-4-(tert-Butyldiphenylsilyloxy)-1-phenyl-2-penten-1-ol 

Relevant articles and documents

Chiral Vinyl Anions for "Carbonyl Umpolung". Highly Stereoselective Addition of a Novel Enantiomerically Pure Vinyllithium Reagent to Aldehydes

The vinyllithium reagent 13 and its enantiomer are generated by a bromine/lithium exchange reaction starting from dibromoalkenes 11 and 12, both available from the corresponding enantiomer of ethyl lactate.When 13 is allowed to react with aldehydes or wit