132273-07-5

Basic information

• Product Name: 2-(p-bromobenzyl)-1,1,3,3-tetramethyl-1,3-disilaisoindoline
• Synonyms: 2-(p-bromobenzyl)-1,1,3,3-tetramethyl-1,3-disilaisoindoline
• CAS NO: 132273-07-5
• Molecular Weight: 376.443
• Mol File: 132273-07-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-(p-bromobenzyl)-1,1,3,3-tetramethyl-1,3-disilaisoindoline(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(p-bromobenzyl)-1,1,3,3-tetramethyl-1,3-disilaisoindoline(132273-07-5)
• EPA Substance Registry System: 2-(p-bromobenzyl)-1,1,3,3-tetramethyl-1,3-disilaisoindoline(132273-07-5)

Safety Data

• Hazardous Substances Data: 132273-07-5(Hazardous Substances Data)

Upstream product

• 583-53-9 2,3-dibromobenzene 
• 589-15-1 1-bromomethyl-4-bromobenzene 
• 153171-22-3 2-(4-bromobenzyl)-1H-isoindole-1,3(2H)-dione 
• 17985-72-7 1,2-bis(dimethylsilyl)benzene 
• 3959-07-7 4-Bromobenzylamine 

Relevant articles and documents

Cholic Acid as an Architectural Component in Biomimetic/Molecular Recogition Chemistry; Synthesis of "Cholaphanes" With Facial Differentiation of Functionality

Facially-differentiated cholaphanes (2) were synthesized in good yields from cholic acid (1).Key steps were the selective 3,7-bis-O-acetylation of methyl cholate (3), the 12-O-benzylation of diacetate 4, and the introduction of a 3β-(p-aminomethyl)phenyl substituent using an arylmanganese reagent and employing the novel ''benzostabase'' N-protection methodology.