13229-35-1

Basic information

• Product Name: N-methyl-N-phenylmethanesulfonamide
• Synonyms: N-methyl-N-phenylmethanesulfonamide
• CAS NO: 13229-35-1
• Molecular Formula: C₈H₁₁NO₂S
• Molecular Weight: 185.24344
• Mol File: 13229-35-1.mol
• Article Data: 8

Chemical Properties

• Appearance: /
• CAS DataBase Reference: N-methyl-N-phenylmethanesulfonamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-methyl-N-phenylmethanesulfonamide(13229-35-1)
• EPA Substance Registry System: N-methyl-N-phenylmethanesulfonamide(13229-35-1)

Safety Data

• Hazardous Substances Data: 13229-35-1(Hazardous Substances Data)

Upstream product

• 1197-22-4 N-phenylmethanesulfonamide 
• 74-88-4 methyl iodide 
• 124-63-0 methanesulfonyl chloride 
• 100-61-8 N-methylaniline 
• 54769-22-1 1-methanesulfonyloxy-1,2,3-benzotriazole 

Downstream Products

• 87712-30-9 ethylcarboxy-N-methyl-N-phenyl-1-methanesulfonamide 
• 92-52-4 biphenyl 
• 61738-44-1 N-methyl-C,N-diphenyl-methanesulfonamide 
• 845280-49-1 C₁₅H₁₄FNO₃S 

Relevant articles and documents

A useful Pd-catalyzed Negishi coupling approach to benzylic sulfonamide derivatives

(Chemical Equation Presented) A mild catalytic system to access diversely functionalized benzylic sulfonamides has been developed. Palladium-catalyzed α-arylation by Negishi cross-coupling of sulfonamide-stabilized anions and a wide range of aryl iodides, bromides, and triflates constitutes a practical strategy for the synthesis of various benzylic sulfonamides.

N-alkylation of N-monosubstituted sulfonamides in ionic liquids

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1H-benzotriazol-1-yl methanesulfonate: A regioselective N-mesylating reagent

1H-Benzotriazol-1-yl methanesulfonate has been found to be an effective reagent in selective mesylation for differentiating amine groups from one another. In a molecule with both primary and secondary amine groups, mesylation only occurred at the primary amine group. When a compound contains both amine and hydroxy groups, the reagent selectively mesylated at the amine groups.