132352-74-0

Basic information

• Product Name: O-(3-(4-methylphenyl)-1-propyl) benzohydroxamate
• CAS NO: 132352-74-0
• Molecular Weight: 269.343
• Mol File: 132352-74-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: O-(3-(4-methylphenyl)-1-propyl) benzohydroxamate(CAS DataBase Reference)
• NIST Chemistry Reference: O-(3-(4-methylphenyl)-1-propyl) benzohydroxamate(132352-74-0)
• EPA Substance Registry System: O-(3-(4-methylphenyl)-1-propyl) benzohydroxamate(132352-74-0)

Safety Data

• Hazardous Substances Data: 132352-74-0(Hazardous Substances Data)

Upstream product

• 5406-39-3 3-(4-methylphenyl)propanol 
• 1866-39-3 4-methylcinnamic acid 
• 54540-53-3 1-(3-bromopropyl)-4-methylbenzene 
• 32685-16-8 potassium benzohydroxamate 

Downstream Products

• 132352-84-2 N-chloro-O-(3-(4-methylphenyl)-1-propyl) benzohydroxamate 

Relevant articles and documents

ALKOXYNITRENIUM ION CYCLISATIONS: EVIDENCE FOR DIFFERENT MECHANISMS IN THE FORMATION OF BENZOXAZINES AND BENZOXAZEPINES.

Deuterium labelling experiments and n.m.r. studies indicate that cyclisations of N-acyl-N-(2-phenylethyloxy)nitrenium ions occur via direct attack at the ortho position to give 3,4-dihydro-1H-2,1-benzoxazines.In contrast N-acyl-N-(3-phenylpropyloxy)nitrenium ions cyclise to 1,3,4,5-tetrahydro-2,1-benzoxazepines through ipso attack followed by 1,2-carbon migration.In both cases hydrogen circumambulation occurs in the sigma complex before aromatisation.