132398-40-4

Basic information

• Product Name: Benzene, (5-hexenylsulfinyl)-
• CAS NO: 132398-40-4
• Molecular Formula: C12H16OS
• Molecular Weight: 208.324
• Mol File: 132398-40-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzene, (5-hexenylsulfinyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (5-hexenylsulfinyl)-(132398-40-4)
• EPA Substance Registry System: Benzene, (5-hexenylsulfinyl)-(132398-40-4)

Safety Data

• Hazardous Substances Data: 132398-40-4(Hazardous Substances Data)

Upstream product

• 1202041-38-0 1-(6-(phenylsulfinyl)hexylsulfinyl)-2-nitrobenzene 
• 125115-14-2 1-chloro-1-phenylsulfanyl-5-hexene 
• 39984-84-4 hex-5-en-1-yl(phenyl)sulfane 
• 193097-39-1 6-chloro-6-phenylsulfinyl-1-hexene 

Relevant articles and documents

O-Nitrophenyl sulfoxides: Efficient precursors for the mild preparation of alkenes

(Chemical Equation Presented) o-Nitrophenyl sulfoxides were found to be efficient synthetic precursors of various alkene types. The elimination occurs in toluene and NaOAc to generate substituted and terminal alkenes. Alkene products were easily obtained in high purity due to the simultaneous precipitation of the o-nitrophenyl sulfenic acid byproduct. The methods described have practical applications for the preparation of unsaturated compounds under mild, thermolytic conditions. 2009 American Chemical Society.

Generation and intramolecular cyclization of α-sulfinyl and α-sulfonyl radicals

α-Phenylsulfinyl and α-Phenylsulfonyl radicals are generated by the reactions of α-chlorosulfoxides and α-chlorosulfones with tributyltin hydride, respectively. High reaction concentration (0.2 M) is required to ensure efficient generations of these radic