132632-77-0Relevant articles and documents
Unexpectedly high diastereomeric induction in the Diels-Alder reaction of quinones with chiral aryl containing 1-alkoxy-3-trimethylsilyloxybuta-1,3-dienes
De Bie,Van Strijdonck,Seerden,Beurskens,Scheeren
, p. 7233 - 7236 (2007/10/02)
Chiral 1-alkoxy-3-trimethylsilyloxybuta-1,3-dienes induce a high diastereomeric excess in the cycioaddition with quinones when the chiral alkoxy group is of the type OCH(CH3)R with R = aryl. Also forR =vinyl. CH2OCH3 the f