132682-80-5

Basic information

• Product Name: Pyridine, 2-(diphenylphosphino)-6-methoxy-
• CAS NO: 132682-80-5
• Molecular Formula: C18H16NOP
• Molecular Weight: 293.305
• Mol File: 132682-80-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Pyridine, 2-(diphenylphosphino)-6-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Pyridine, 2-(diphenylphosphino)-6-methoxy-(132682-80-5)
• EPA Substance Registry System: Pyridine, 2-(diphenylphosphino)-6-methoxy-(132682-80-5)

Safety Data

• Hazardous Substances Data: 132682-80-5(Hazardous Substances Data)

Upstream product

• 40473-07-2 6-bromo-2-methoxypyridine 
• 1079-66-9 chloro-diphenylphosphine 
• 17228-64-7 6-chloro-2-methoxypyridine 

Downstream Products

• 143890-27-1 {Pd(C₅H₃N(P(C₆H₅)2)(OCH₃))Cl₂}2 
• 143890-26-0 {Pd(CNC(CH₃)3)(C₅H₃N(P(C₆H₅)2)(OCH₃))Cl₂} 
• 143890-25-9 {Au(P(C₆H₅)3)(C₅H₃N(P(C₆H₅)2)(OCH₃))}⁽¹⁺⁾*PF₆^(1-)={Au(P(C₆H₅)3)(C₅H₃N(P(C₆H₅)2)(OCH₃))}PF₆ 
• 1260401-69-1 cis-[Cl₂Pt(2-methoxy-6-diphenylphosphanylpyridine)2] 
• 143890-19-1 {Rh(CO)(C₅H₃N(P(C₆H₅)2)(OCH₃))2Cl} 
• 143890-23-7 {Rh(CO)(C₅H₃N(P(C₆H₅)2)(OCH₃))Cl}2 
• 143890-17-9 Rh(C₈H₁₂)(C₅H₃N(P(C₆H₅)2)(OCH₃))Cl 

Relevant articles and documents

Noncryogenic synthesis of functionalized 2-methoxypyridines by halogen-magnesium exchange using lithium dibutyl(isopropyl)magnesate(1-) and lithium chloride

2-Methoxypyridines functionalized in the 3-, 5-, or 6-position and 2,6-dimethoxypyridines functionalized in the 3-position were prepared from the corresponding bromo or iodo analogues by using lithium dibutyl(isopropyl) magnesate(1-) and lithium chloride

Electrosynthesis of triorganylphosphines from organic halides and chlorophosphines, catalyzed by nickel complexes

The possibility of cross coupling of organic halides and chlorophosphines under the action of electrochemically generated Ni(0) complexes of 2,2′-bipy is shown. The final triorganylphosphines are formed by several pathways, including reaction of the σ complex of ArNiX with chlorophosphine and electron transfer-induced reductive elimination of Ph2PArNiX, leading to the cross-coupling product.

Carbonylation catalyst system

A catalyst system, which comprises: a) a source of a Group VIII metal; b) a phosphine having an aromatic substituent which contains an imino nitrogen atom; c) a source of protons; and d) a tertiary amine.