13271-68-6 Usage
Description
2-Furyldimethylsilane is a chemical compound with the molecular formula C7H10OSi. It is a colorless liquid with a sweet, fruity odor. 2-Furyldimethylsilane is recognized for its unique chemical properties and reactivity, making it a versatile and important intermediate in the field of organic synthesis.
Uses
Used in Pharmaceutical Industry:
2-Furyldimethylsilane is used as a building block for the synthesis of various organic compounds, particularly in the production of pharmaceuticals. Its unique properties and reactivity contribute to the development of new drugs and medicinal compounds.
Used in Agrochemical Industry:
In the agrochemical sector, 2-Furyldimethylsilane serves as a key component in the synthesis of various agrochemicals. Its role in creating effective and innovative products is vital for agricultural advancements.
Used as a Reagent in Organic Reactions:
2-Furyldimethylsilane is utilized as a reagent in the preparation of sila-heterocycles, which are important in various chemical applications. Its ability to participate in cross-coupling reactions in organometallic chemistry further expands its utility in organic synthesis.
Check Digit Verification of cas no
The CAS Registry Mumber 13271-68-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,2,7 and 1 respectively; the second part has 2 digits, 6 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 13271-68:
(7*1)+(6*3)+(5*2)+(4*7)+(3*1)+(2*6)+(1*8)=86
86 % 10 = 6
So 13271-68-6 is a valid CAS Registry Number.
InChI:InChI=1/C6H10OSi/c1-8(2)6-4-3-5-7-6/h3-5,8H,1-2H3
13271-68-6Relevant articles and documents
Silapyran and Silacyclobutene Formation in the Gas-Phase Pyrolysis of 2-(Dimethylsilyl)furan
Barton, Thomas J.,Groh, Brian L.
, p. 8297 - 8299 (1985)
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Reactions of heteroarylhydrosilanes with dichlorocarbene under phase-transfer conditions
Lukevics, E.,Sturkovich, R.,Goldberg, Yu.,Gaukhman, A.
, p. 19 - 26 (1988)
The reactions of dimethyl(2-thienyl)-, methyl-, tri(2-thienyl)- and dimethyl(2-furyl)silanes (I-IV, respectively) with dichlorocarbene generated from sodium trichloroacetate under solid-liquid phase-transfer conditions afford the corresponding dichloromethylsilanes in 38-66percent yield.The reactivity of the thienylsilanes decreases with the number of electron-accepting thienyl substituents at the silicon atom.Using the competition reactions, the relative rate constants for the reaction of dichlorocarbene insertion into the Si-H bond of thienyl- and furyl-silanes (I and IV) were measured.The reactivity of these silanes was found to be greater than had been expected taking as a basis the Taft ?* constants for the substituent at the silicon atom.This is apparently due to the existence of a p?-d? interaction between the heterocyclic ?-system and the d-orbitals of silicon.
Cleavage of Si-C and Ge-C bonds in heterylsilanes and -germanes by organolithium reagents
Gevorgyan, Vladimir,Borisova, Larisa,Lukevics, Edmunds
, p. 381 - 387 (2007/10/02)
Organolithium reagents RLi can cleave Si-C and Ge-C bonds in heterylsilanes and -germanes substituting furyl, dihydrofuryl and dihydropyranyl groups for the organolithium residue R.
