1327274-42-9

Basic information

• Product Name: benzo[d]oxazol-2-yl(3-nitrophenyl)methanone
• Synonyms: benzo[d]oxazol-2-yl(3-nitrophenyl)methanone
• CAS NO: 1327274-42-9
• Molecular Weight: 268.229
• Mol File: 1327274-42-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: benzo[d]oxazol-2-yl(3-nitrophenyl)methanone(CAS DataBase Reference)
• NIST Chemistry Reference: benzo[d]oxazol-2-yl(3-nitrophenyl)methanone(1327274-42-9)
• EPA Substance Registry System: benzo[d]oxazol-2-yl(3-nitrophenyl)methanone(1327274-42-9)

Safety Data

• Hazardous Substances Data: 1327274-42-9(Hazardous Substances Data)

Upstream product

• 121-89-1 3-Nitroacetophenone 
• 88-75-5 2-hydroxynitrobenzene 
• 273-53-0 benzoxazole 
• 86440-77-9 1-bromo-2-(3-nitrophenyl)acetylene 
• 95-55-6 2-amino-phenol 
• 444681-65-6 1,1-dibromo-2-(3-nitrophenyl)ethene 

Relevant articles and documents

Fe/S-Catalyzed synthesis of 2-benzoylbenzoxazoles and 2-quinolylbenzoxazolesviaredox condensation ofo-nitrophenols with acetophenones and methylquinolines

An Fe/S catalyst generatedin situfrom FeCl2·4H2O and elemental sulfur S8in the presence of a tertiary amine as a base was found to catalyze efficiently a 6e?redox condensation ofo-nitrophenols with acetophenones and methylquinolines. The condensed products 2-benzoylbenzoxazoles and 2-quinolylbenzoxazoles were obtained in reasonable yields with water as the only byproduct at a temperature as low as 80 °C.

Palladium(II)/N-heterocyclic carbene-catalyzed direct C-H acylation of heteroarenes with N-acylsaccharins

N-Acylsaccharin represents a facile acyl group transfer agent to heteroarenes in the presence of Pd(II)/NHC complexes appended with a pyrene unit. Catalytic acylation of heteroarenes was enhanced by the noncovalent interaction between the pyrene unit and

Synthesis of heteroaryl ketones via tandem reaction of 1,1-dibromoethenes

A novel method for the synthesis of heteroaryl ketones through one-pot tandem reaction of 1,1-dibromoethenes with 2-amino(thio)phenols promoted by TBAF·3H2O and RuCl3(5%)/air was developed. This novel method includes several reactions in one-pot and utilizes economical yet efficient reagents to generate synthetically and biologically interesting heteroaryl ketones under mild conditions with good efficiency.