132735-34-3

Basic information

• Product Name: (2S,4R)-2-methoxycarbonyl-4-methyl-2-phenyl-1,3-dioxane
• Synonyms: (2S,4R)-2-methoxycarbonyl-4-methyl-2-phenyl-1,3-dioxane
• CAS NO: 132735-34-3
• Molecular Weight: 236.268
• Mol File: 132735-34-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2S,4R)-2-methoxycarbonyl-4-methyl-2-phenyl-1,3-dioxane(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,4R)-2-methoxycarbonyl-4-methyl-2-phenyl-1,3-dioxane(132735-34-3)
• EPA Substance Registry System: (2S,4R)-2-methoxycarbonyl-4-methyl-2-phenyl-1,3-dioxane(132735-34-3)

Safety Data

• Hazardous Substances Data: 132735-34-3(Hazardous Substances Data)

Upstream product

• 15206-55-0 methyl 2-oxo-2-phenylacetate 
• 6290-03-5 (R)-butane-1,3-diol 

Downstream Products

• 132735-38-7 (2S,4R)-2-acetoxymethyl-4-methyl-2-phenyl-1,3-dioxane 
• 144404-99-9 (2S,4R)-2-Formyl-4-methyl-2-phenyl-1,3-dioxane 
• 132735-35-4 (2S,4R)-2-hydroxymethyl-4-methyl-2-phenyl-1,3-dioxane 

Relevant articles and documents

Distinction of Diastereofaces at the α-Position of Chiral Cyclic Acetals

Key words: chiral acetal; asymmetric 1,2-addition; asymmetric 1,4-addition; C2 symmetry; determination of optical purity; chiral carboxylic acid Asymmetric 1,2- and 1,4-additions to substrates with an acetal as a chiral auxiliary have been studied.Among the tested substrates, C2-symmetrical 5c was most effective for 1,2-addition with MeTi(O-iPr)3.Furthermore, C2-symmetrical carbinol 5b has been found to be a potent 1H-NMR reagent for determination of optical purity of carboxylic acids with a chiral center at the α-position.