13274-47-0

Basic information

• Product Name: Hydrazinecarboxylic acid, 2-[[(4-nitrophenyl)amino]carbonyl]-, ethyl ester
• CAS NO: 13274-47-0
• Molecular Formula: C10H12N4O5
• Molecular Weight: 268.229
• Mol File: 13274-47-0.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Hydrazinecarboxylic acid, 2-[[(4-nitrophenyl)amino]carbonyl]-, ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Hydrazinecarboxylic acid, 2-[[(4-nitrophenyl)amino]carbonyl]-, ethyl ester(13274-47-0)
• EPA Substance Registry System: Hydrazinecarboxylic acid, 2-[[(4-nitrophenyl)amino]carbonyl]-, ethyl ester(13274-47-0)

Safety Data

• Hazardous Substances Data: 13274-47-0(Hazardous Substances Data)

Upstream product

• 100-28-7 4-Nitrophenyl isocyanate 
• 4114-31-2 ethylhydrazine carboxylate 
• 62-23-7 4-nitro-benzoic acid 
• 122-04-3 4-nitro-benzoyl chloride 
• 2733-41-7 4-nitrobenzoyl azide 
• 50686-13-0 (4-nitro-phenyl)-carbamic acid-(4-nitro-phenyl ester) 

Downstream Products

• 410535-09-0 1-ethoxycarbonyl-4-(4-aminophenyl)semicarbazide 
• 140707-19-3 4-(4-aminophenyl)-1,2,4-triazolidine-3,5-dione 
• 13274-45-8 4-(p-nitrophenyl)urazole 

Relevant articles and documents

URAZOLE COMPOUNDS

The present invention relates to a compound of formula (I) or a stereoisomer, enantiomer, racemic, or tautomer thereof, (I) wherein R1, R2, R3, R4, R5, R6, R7, L1 and Q1 have the meaning defined in the claims and the description. The present invention also relates to a process for the preparation of the compound of formula (I). The present invention also relates to the use of a compound of formula (I) as an in situ precursor of a triazolinedione reagent for the functionalization of enes, dienes, aryl and heteroaryl systems via the ene reactions, Diels-Alder reactions, and electrophilic aromatic substitution reactions of said reagent. The present invention also relates to the use of a compound of formula (I) in polymers, membranes, adhesives, foams, sealants, molded articles, films, extruded articles, fibers, elastomers, polymer based additives, pharmaceutical and biomedical products, varnishes, paints, coatings, inks, composite material, organic LEDs, organic semiconductors, conducting organic polymers, or 3D printed articles. The present invention also relates to article comprising said compound of formula (I) and to a process for reshaping and/or repairing said article.

Novel and efficient synthesis of 4-substituted-1,2,4-triazolidine-3,5- diones from anilines

A simple and efficient three-step synthetic procedure for the preparation of 4-substituted phenyl derivatives of 1,2,4-triazolidindiones (urazoles), starting from anilines, has been developed. In this method, aniline derivatives were reacted with 4-nitrophenyl chloroformate to provide corresponding carbamate derivatives. In the second step, semicarbazide derivatives were prepared from these carbamates by reaction with ethyl carbazate. The cyclization reaction of corresponding semicarbazides furnished 1,2,4-triazolidindiones in high yields. Copyright Taylor & Francis Group, LLC.

Synthesis of novel azo dyes derived from 4-phenylurazole

A novel and convenient method for the preparation of 4-(4-aminophenyl) urazole has been developed. Protic diazotization of amino group of this compound and subsequent coupling reaction with some electron rich aromatic compounds such as phenols, naphthols, and anilines lead to the formation of novel azo dyes with a phenylurazole linkage in moderate to high yields.