132819-80-8

Basic information

• Product Name: 2-benzylallyl ethyl carbonate
• Synonyms: 2-benzylallyl ethyl carbonate
• CAS NO: 132819-80-8
• Molecular Weight: 220.268
• Mol File: 132819-80-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-benzylallyl ethyl carbonate(CAS DataBase Reference)
• NIST Chemistry Reference: 2-benzylallyl ethyl carbonate(132819-80-8)
• EPA Substance Registry System: 2-benzylallyl ethyl carbonate(132819-80-8)

Safety Data

• Hazardous Substances Data: 132819-80-8(Hazardous Substances Data)

Upstream product

• 1589-82-8 phenylmagnesium bromide 
• 20593-63-9 2-Benzylacrylic acid ethyl ester 
• 30457-89-7 2-benzylallyl alcohol 
• 541-41-3 chloroformic acid ethyl ester 

Downstream Products

• 132819-89-7 ethyl 3-(2-benzylallyl)-1-tosylindole-2-carboxylate 
• 1639790-56-9 5-benzyl-3-(1,3-dithiolan-2-ylidene)hex-5-en-2-one 
• 1639790-58-1 4-benzyl-2-(1,3-dithiolan-2-ylidene)-1-(furan-2-yl)pent-4-en-1-one 

Relevant articles and documents

Palladium-catalyzed oxidative heck-type allylation of β,β- disubstituted enones with allyl carbonates

The palladium-catalyzed oxidative Heck-type allylation of β,β-disubstituted enones, i.e., α-oxoketene dithioacetals, was efficiently realized with allyl carbonates, providing a concise route to highly functionalized dienes. The present synthetic methodology utilizes the substrate activation strategy to activate the C-H bond of β,β-disubstituted enones by introduction of a 1,2-dithiolane functionality to make the enone substrate highly polarized and thus increase its reactivity, demonstrating rare examples for transition metal-catalyzed allylic substitution of ss,ss-disubstituted enones through a Heck-type allylation process.