13290-29-4

Basic information

• Product Name: (2-bromo-ethyl)-(4-nitro-phenyl)-sulfide
• Synonyms: (2-bromo-ethyl)-(4-nitro-phenyl)-sulfide
• CAS NO: 13290-29-4
• Molecular Weight: 262.127
• Mol File: 13290-29-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2-bromo-ethyl)-(4-nitro-phenyl)-sulfide(CAS DataBase Reference)
• NIST Chemistry Reference: (2-bromo-ethyl)-(4-nitro-phenyl)-sulfide(13290-29-4)
• EPA Substance Registry System: (2-bromo-ethyl)-(4-nitro-phenyl)-sulfide(13290-29-4)

Safety Data

• Hazardous Substances Data: 13290-29-4(Hazardous Substances Data)

Upstream product

• 106-93-4 ethylene dibromide 
• 1849-36-1 para-nitrobenzenethiol 
• 100-05-0 4-nitrobenzenediazonium chloride 
• 100-00-5 4-chlorobenzonitrile 
• 13287-76-8 2-(p-nitrophenylthio)ethanol 

Downstream Products

• 5535-55-7 1-nitro-4-(vinylsulfonyl)benzene 
• 206874-35-3 6,7-dimethoxy-2-[2-(4-nitro-phenylsulfanyl)-ethyl]-1,2,3,4-tetrahydro-isoquinoline 
• 115256-42-3 N-[4-(2-{[2-(4-Methanesulfonylamino-phenylsulfanyl)-ethyl]-methyl-amino}-ethyl)-phenyl]-methanesulfonamide 
• 115256-41-2 1-(4-Aminophenylthio)-2-[N-(4-aminophenethyl)-N-methylamino]ethane 
• 115256-40-1 2-[N-methyl-N-(4-nitrophenethyl)amino]-1-(4-nitrophenylthio)ethane 

Relevant articles and documents

Diastereoselective Monofluorocyclopropanation Using Fluoromethylsulfonium Salts

Diarylfluoromethylsulfonium salts, alternatives to freons or advanced fluorinated building blocks, are bench stable and easy-to-use sources of direct fluoromethylene (:CHF) transfer to alkenes. These salts enabled development of a trans-selective monofluorinated Johnson-Corey-Chaykovsky reaction with vinyl sulfones or vinyl sulfonamides to access synthetically challenging monofluorocyclopropane scaffolds. The described method offers rapid access to monofluorinated cyclopropane building blocks with further functionalization opportunities to deliver more complex synthetic targets diastereoselectively.