1329656-50-9Relevant articles and documents
A radical procedure for the anti-markovnikov hydroazidation of alkenes
Kapat, Ajoy,Koenig, Andreas,Montermini, Florian,Renaud, Philippe
supporting information; experimental part, p. 13890 - 13893 (2011/10/31)
A one-pot procedure for the efficient hydroazidation of alkenes involving hydroboration with catecholborane followed by reaction with benzenesulfonyl azide in the presence of a radical initiator is described. The regioselectivity is controlled by the hydroboration step and corresponds in most cases to an anti-Markovnikov regioselectivity. This procedure is applicable to a wide range of alkenes and gives excellent results with 1,2-disubstituted and trisubstituted alkenes.