1330191-23-5

Basic information

• Product Name: 1,3-bis(2,6-dimethylphenyl)-2-(diphenylphosphanyl)-1,3,2-diazaphospholidine
• Synonyms: 1,3-bis(2,6-dimethylphenyl)-2-(diphenylphosphanyl)-1,3,2-diazaphospholidine
• CAS NO: 1330191-23-5
• Molecular Weight: 482.545
• Mol File: 1330191-23-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,3-bis(2,6-dimethylphenyl)-2-(diphenylphosphanyl)-1,3,2-diazaphospholidine(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-bis(2,6-dimethylphenyl)-2-(diphenylphosphanyl)-1,3,2-diazaphospholidine(1330191-23-5)
• EPA Substance Registry System: 1,3-bis(2,6-dimethylphenyl)-2-(diphenylphosphanyl)-1,3,2-diazaphospholidine(1330191-23-5)

Safety Data

• Hazardous Substances Data: 1330191-23-5(Hazardous Substances Data)

Upstream product

• 674783-84-7 2-chloro-1,3-(2,6-dimethylphenyl)-1,3,2-diazaphospholidine 
• 829-85-6 diphenylphosphane 
• 72991-60-7 N¹,N²-bis(2,6-dimethylphenyl)ethane-1,2-diamine 
• 49673-43-0 N¹,N²-bis(2,6-dimethylphenyl)ethane-1,2-diimine 

Downstream Products

• 1330191-27-9 1,1',3,3'-tetrakis(2,6-dimethylphenyl)-2,2'-bis(1,3,2-diazaphospholidinyl) 
• 1101-41-3 Tetraphenyldiphosphin 

Relevant articles and documents

Structure-Analytical Investigations of P-Substituted 1,3,2- Diazaphospholidines

2-Diphenylphosphanyl-1,3,2-diazaphospholidines were prepared via metathesis from 2-chloro-1,3,2-diazaphospholidines and LiPPh2. For some of the products, symmetrisation to tetraphenyldiphosphane and 2,2′-bis-1,3,2- diazaphospholidinyls was observed. Most of the derivatives were characterised by single-crystal X-ray diffraction, which showed that all compounds studied feature elongated exocyclic P-Cl or P-P-bonds, respectively. The extent of this bond lengthening is in the P-phosphanyl-substituted species similar and in the P-chloro-derivatives less pronounced than in corresponding CC-unsaturated 1,3,2-diazaphospholenes. Structure correlation involving comparison of exocyclic P-X and endocyclic P-N distances suggests that n(N)/σ(P-X) hyperconjugation contributes strongly to the bond lengthening and induces a perceptible weakening of the P-P bonds in 2-diphenylphosphanyl-1,3,2- diazaphospholidines, which should render these compounds interesting substrates for P-P bond activation reactions. Copyright