13318-11-1Relevant articles and documents
A convenient preparation of di-p-chlorobenzyl azodicarboxylate (DCAD) for mitsunobu couplings
Taft, Benjamin R.,Swift, Elizabeth C.,Lipshutz, Bruce H.
, p. 332 - 334 (2009)
Gram-scale synthesis of pure, bench-stable solid di-p-chlorobenzyl azodicarboxylate (DCAD) is performed in two steps without resorting to chromatography. This novel reagent effects Mitsunobu couplings with yields comparable to DEAD or DIAD, while addressi
METHOD FOR PRODUCING GLYCIDYL ESTER
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Paragraph 0032; 0034-0038, (2017/11/09)
PROBLEM TO BE SOLVED: To provide a production method which makes it possible to obtain glycidyl ester with high yields from the ester exchange reaction between ester and glycidol with a convenient catalyst in a mild reaction condition. SOLUTION: Glycidyl ester is produced by the ester exchange reaction between ester and glycidol in the presence of a polystyrene-carrying quaternary ammonium salt. SELECTED DRAWING: None COPYRIGHT: (C)2017,JPOandINPIT
Regioselective opening of an oxirane system with trifluoroacetic anhydride. A general method for the synthesis of 2-monoacyl- and 1,3-symmetrical triacylglycerols
Stamatov, Stephan D.,Stawinski, Jacek
, p. 3659 - 3669 (2007/10/03)
A trifluoroacetic anhydride-catalyzed opening of the oxirane system of glycidyl esters with a simultaneous migration of the acyl group provides a new, efficient entry to either 2-monoacylglycerols (2-MAG) or 1,3-symmetrical triglycerides (1,3-STG) as potential prodrug frameworks.