13320-38-2Relevant articles and documents
Synthesis and structure of silylmethylsilatranes
Gevorgyan, Vladimir,Borisova, Larisa,Vjater, Armand,Popelis, Juris,Belyakov, Sergei,Lukevics, Edmunds
, p. 73 - 80 (1994)
New alkoxysilylmethylsilatranes have been obtained from the reaction of silylmethylsilatrane with alcohols in the presence of H2PtCl6*6H2O.Methylphenylsilylmethylsilatrane (1) reacted with H2O in the presence of Pd to give methylphenyl
Catalytic Dehydrogenative Coupling of Hydrosilanes with Alcohols for the Production of Hydrogen On-demand: Application of a Silane/Alcohol Pair as a Liquid Organic Hydrogen Carrier
Ventura-Espinosa, David,Carretero-Cerdán, Alba,Baya, Miguel,García, Hermenegildo,Mata, Jose A.
supporting information, p. 10815 - 10821 (2017/08/18)
The compound [Ru(p-cym)(Cl)2(NHC)] is an effective catalyst for the room-temperature coupling of silanes and alcohols with the concomitant formation of molecular hydrogen. High catalyst activity is observed for a variety of substrates affording quantitative yields in minutes at room temperature and with a catalyst loading as low as 0.1 mol %. The coupling reaction is thermodynamically and, in the presence of a Ru complex, kinetically favourable and allows rapid molecular hydrogen generation on-demand at room temperature, under air, and without any additive. The pair silane/alcohol is a potential liquid organic hydrogen carrier (LOHC) for energy storage over long periods in a safe and secure way. Silanes and alcohols are non-toxic compounds and do not require special handling precautions such as high pressure or an inert atmosphere. These properties enhance the practical applications of the pair silane/alcohol as a good LOHC in the automotive industry. The variety and availability of silanes and alcohols permits a pair combination that fulfils the requirements for developing an efficient LOHC.
Copper nanoparticles supported on doped graphenes as catalyst for the dehydrogenative coupling of silanes and alcohols
Blez, Juan F.,Primo, Ana,Asiri, Abdullah M.,lvaro, Mercedes,Garc, Hermenegildo
supporting information, p. 12581 - 12586 (2015/04/16)
Copper nanoparticles (NPs) supported on a series of undoped and doped graphene materials (Gs) have been obtained by pyrolysis of alginate or chitosan biopolymers, modified or not with boric acid, containing Cu2+ ions at 900 °C under inert atmosphere. The resulting Cu-G materials containing about 17 wt% Cu NPs (from 10 to 200 nm) exhibit high catalytic activity for the dehydrogenative coupling of silanes with alcohols. The optimal material consisting on Cu-(B)G is more efficient than Cu NPs on other carbon supports.
